METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90

Uses Synthesis

Product Name: METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
CAS No.: 33689-29-1
Chemical Name: METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90
Synonyms: Methyl 1-Hydroxycyclopropane-1-carboxylate;Methyl 1-Hydroxycyclopropanecarboxylate;METHYL 1-HYDROXY-1-CYCLOPROPANE;METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYL;METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90;1-Hydroxycyclopropanecarboxylic Acid Methyl Ester;Methyl 1-hydroxy-1-cyclopropane carboxylate, 90% 5GR;Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester;1-hydroxy-Cyclopropanecarboxylic acid methyl ester (8CI 9CI ACI);Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester (8CI, 9CI, ACI)
CBNumber: CB9502042
Molecular Formula: C5H8O3
Formula Weight: 116.12
MOL File: 33689-29-1.mol

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METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Property

Boiling point:: 70°C/13mmHg
Density: 1.346±0.06 g/cm3(Predicted)
Flash point:: 17℃
storage temp.: Sealed in dry,2-8°C
solubility: Dichloromethane, Methanol
form: Liquid
pka: 13.14±0.20(Predicted)
color: Clear yellow

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Safety

Risk Statements: 11
Safety Statements: 16
RIDADR: 3277
HS Code: 29162090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: H825150
Product name: 1-HydroxycyclopropanecarboxylicAcidMethylEster
Packaging: 1g
Price: $395
Updated: 2021/12/16

Matrix Scientific

Product number: 114023
Product name: Methyl 1-hydroxy-1-cyclopropanecarboxylate
Purity: 95%
Packaging: 1g
Price: $449
Updated: 2021/12/16

ChemScene

Product number: CS-W005559
Product name: Methyl1-hydroxycyclopropanecarboxylate
Purity: ≥97.0%
Packaging: 5g
Price: $150
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2229-1-63
Product name: Methyl 1-hydroxycyclopropane-1-carboxylate
Purity: 97.0%
Packaging: 1g
Price: $190
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK623387
Product name: Methyl1-hydroxy-1-cyclopropanecarboxylate
Purity: 90%
Packaging: 1g
Price: $192
Updated: 2021/12/16

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METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Chemical Properties,Usage,Production

Uses

1-Hydroxycyclopropanecarboxylic Acid Methyl Ester is a compound useful in organic synthesis.

Synthesis

Methyl 1-aminocyclopropylcarboxylate (3.41g, 29.6mmol, 1.0eq) was dissolved in 40ml of sulfuric acid aqueous solution A (prepared by adding 1.62mL of 98% concentrated sulfuric acid to water, the molar equivalent of sulfuric acid was 1.0eq), ice The bath was cooled to 0-5° C., 10 ml of sodium nitrite (2.25 g, 32.6 mmol, 1.1 eq) aqueous solution was added to the reaction solution, and the mixture was stirred at room temperature for 1 hour. Then, the above reaction was added dropwise to 100 ml of refluxing sulfuric acid aqueous solution B (prepared by adding 1.62 mL of 98% concentrated sulfuric acid to water, and the molar equivalent of sulfuric acid was 1.0 eq). After the dropwise addition was completed, the heating was stopped, cooled to room temperature, and the reaction was detected by TLC, extracted three times with ethyl acetate (3*100 mL), the organic phases were combined, dried with anhydrous magnesium sulfate, filtered, and the organic phase was concentrated to obtain 1-hydroxyl -Methyl 1-cyclopropanecarboxylate (2.57 g, 22.1 mmol), colorless oily liquid, yield 74.8%.

Chemical Properties

Clear yellow liquid

Uses

1-Hydroxycyclopropanecarboxylic Acid Methyl Ester (cas# 33689-29-1) is a compound useful in organic synthesis.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 1269, 1984 DOI: 10.1016/S0040-4039(01)80131-3

METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 Suppliers

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View Lastest Price from METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90 manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: METHYL 1-HYDROXY-1-CYCLOPROPANE 33689-29-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2024-08-15

Henan Aochuang Chemical Co.,Ltd.

Product: methyl 1-hydroxycyclopropane-1-carboxylate 33689-29-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-26

Career Henan Chemical Co

Product: METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE 33689-29-1
Price: US $6.60/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg -1000kg
Release date: 2020-01-02

33689-29-1, METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90Related Search:

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METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYLATE, 90

1-Hydroxycyclopropanecarboxylic Acid Methyl Ester

Methyl 1-hydroxy-1-cyclopropane carboxylate, 90% 5GR

Methyl 1-Hydroxycyclopropane-1-carboxylate

Methyl 1-Hydroxycyclopropanecarboxylate

Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester

Cyclopropanecarboxylic acid, 1-hydroxy-, methyl ester (8CI, 9CI, ACI)

1-hydroxy-Cyclopropanecarboxylic acid methyl ester (8CI 9CI ACI)

METHYL 1-HYDROXY-1-CYCLOPROPANE

METHYL 1-HYDROXY-1-CYCLOPROPANE CARBOXYL

33689-29-1

Miscellaneous Reagents