CIS-1,3-DICHLOROPROPENE
- Product Name
- CIS-1,3-DICHLOROPROPENE
- CAS No.
- 10061-01-5
- Chemical Name
- CIS-1,3-DICHLOROPROPENE
- Synonyms
- (z)-1,3-dichloro-1-propene;cis-dcp;CIS-1,3-CHLOROPROPENE;3-dichloro-(z)-propen;CIS-1,3-DICHLOROPROPENE;1,3-CIS-DICHLOROPROPENE;(Z)-1,3-Dichloropropene;3-dichloro-(z)-1-propen;1,3-DICHLOROPROPENE(CIS);(1Z)-1,3-Dichloropropene
- CBNumber
- CB9680157
- Molecular Formula
- C3H4Cl2
- Formula Weight
- 110.97
- MOL File
- 10061-01-5.mol
CIS-1,3-DICHLOROPROPENE Property
- Melting point:
- -50 °C
- Boiling point:
- 104 °C(lit.)
- Density
- 1.225 g/mL at 25 °C(lit.)
- vapor pressure
- 111.6 at 50 °C, 687.8 at 100 °C (Wilding et al., 2002)
- refractive index
- n20/D 1.4675(lit.)
- Flash point:
- 75 °F
- storage temp.
- 0-6°C
- solubility
- Chloroform (Soluble), Methanol (Slightly)
- form
- Oil
- color
- Colourless
- Water Solubility
- 1.071g/L(30 ºC)
- Merck
- 14,3075
- Henry's Law Constant
- 1.23 x 10-3 atm?m3/molat 20 °C, 2.77 at 40 °C (static headspace-GC, Kim et al., 2003)
- Exposure limits
- ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
- Stability:
- Stable. Flammable. Incompatible with strong oxidizing agents, aluminium and its alloys, active metals, halogens, some metal salts. May be light sensitive.
- LogP
- 1.82 at 20℃ and pH5.83-7.78
- Surface tension
- 69.6mN/m at 976.8mg/L and 20.2℃
- CAS DataBase Reference
- 10061-01-5(CAS DataBase Reference)
- NIST Chemistry Reference
- 1-Propene, 1,3-dichloro-, (Z)-(10061-01-5)
- EPA Substance Registry System
- cis-1,3-Dichloropropene (10061-01-5)
Safety
- Hazard Codes
- T,N,F
- Risk Statements
- 10-20/21-25-36/37/38-43-50/53-52/53-39/23/24/25-23/24/25-11-65-24/25-20
- Safety Statements
- 36/37-45-60-61-16-7
- RIDADR
- UN 2047 3/PG 2
- WGK Germany
- 3
- RTECS
- UC8325000
- HazardClass
- 3.2
- PackingGroup
- III
- Hazardous Substances Data
- 10061-01-5(Hazardous Substances Data)
- Toxicity
- LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats is 713 and 470 mg/kg, respectively (Verschueren, 1983).
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H304May be fatal if swallowed and enters airways
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H335May cause respiratory irritation
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P331Do NOT induce vomiting.
N-Bromosuccinimide Price
- Product number
- 377414
- Product name
- cis-1,3-Dichloropropene
- Purity
- 97%
- Packaging
- 1ml
- Price
- $75
- Updated
- 2024/03/01
- Product number
- D2792
- Product name
- cis-1,3-Dichloropropene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $127
- Updated
- 2023/01/07
- Product number
- HCH0014058
- Product name
- CIS-1,3-DICHLORO-1-PROPENE
- Purity
- 95.00%
- Packaging
- 1ML
- Price
- $610.42
- Updated
- 2021/12/16
CIS-1,3-DICHLOROPROPENE Chemical Properties,Usage,Production
Chemical Properties
colourless to amber liquid
Chemical Properties
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.
Physical properties
Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).
Uses
The isomeric mixture is used as a soil fumigant and a nematocide.
Definition
ChEBI: The (Z)-isomer of 1,3-dichloropropene.
General Description
Colorless to amber liquid with a sweetish odor.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
CIS-1,3-DICHLOROPROPENE may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.
Fire Hazard
Flash point data for CIS-1,3-DICHLOROPROPENE are not available, however literature sources indicate that CIS-1,3-DICHLOROPROPENE is flammable.
Safety Profile
Confirmed carcinogen with experimental neoplastigenic data. Human mutation data reported. A dangerous fire hazard when exposed to heat, flame, or oxidzers. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS , ALIPHATIC .
Potential Exposure
Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.
Environmental Fate
Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen-
1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized
to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors
et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation
in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted
at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to
volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser,
1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol
and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993).
Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation
of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl
chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon
et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C
using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6
minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic
phosgene (Sittig, 1985).
Solubility in organics
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.
Solubility in water
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.
Shipping
UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.
Incompatibilities
Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.
Waste Disposal
Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
CIS-1,3-DICHLOROPROPENE Preparation Products And Raw materials
Raw materials
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View Lastest Price from CIS-1,3-DICHLOROPROPENE manufacturers
- Product
- (Z)-1,3-Dichloro-1-propene 10061-01-5
- Price
- US $9.80/KG
- Min. Order
- 1KG
- Purity
- ＞98%HPLC
- Supply Ability
- 20 tons
- Release date
- 2020-02-06