4-(Methylmercapto)aniline
- Product Name
- 4-(Methylmercapto)aniline
- CAS No.
- 104-96-1
- Chemical Name
- 4-(Methylmercapto)aniline
- Synonyms
- 4-(METHYLTHIO)ANILINE;AKOS 91153;P-THIOANISIDINE;P-AMINOTHIOANISOLE;4-AMINOTHIOANISOLE;TIMTEC-BB SBB006658;p-Thiomethoxyaniline;4-(Methylmercapto)an;p-(methylthio)-anilin;P-(METHYLTHIO)ANILINE
- CBNumber
- CB9685172
- Molecular Formula
- C7H9NS
- Formula Weight
- 139.22
- MOL File
- 104-96-1.mol
4-(Methylmercapto)aniline Property
- Melting point:
- 156-158 °C
- Boiling point:
- 272-273 °C(lit.)
- Density
- 1.119 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.639(lit.)
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Liquid
- pka
- 4.35(at 25℃)
- color
- Clear orange to brown-red
- Sensitive
- Stench
- BRN
- 774506
- InChI
- InChI=1S/C7H9NS/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
- InChIKey
- YKFROQCFVXOUPW-UHFFFAOYSA-N
- SMILES
- C1(N)=CC=C(SC)C=C1
- CAS DataBase Reference
- 104-96-1(CAS DataBase Reference)
- NIST Chemistry Reference
- 4-Methylmercaptoaniline(104-96-1)
- EPA Substance Registry System
- Benzenamine, 4-(methylthio)- (104-96-1)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-36-37/39
- RIDADR
- 2810
- WGK Germany
- 3
- RTECS
- BY6302000
- F
- 2-8-10-13
- Hazard Note
- Irritant/Stench
- TSCA
- T
- HazardClass
- IRRITANT, STENCH
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29309090
- Toxicity
- LD50 orl-qal: 562 mg/kg AECTCV 12,355,83
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M54503
- Product name
- 4-(Methylthio)aniline
- Purity
- 98%
- Packaging
- 5g
- Price
- $31.2
- Updated
- 2024/03/01
- Product number
- M54503
- Product name
- 4-(Methylthio)aniline
- Purity
- 98%
- Packaging
- 25g
- Price
- $54.06
- Updated
- 2024/03/01
- Product number
- M1674
- Product name
- 4-(Methylthio)aniline
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $154
- Updated
- 2024/03/01
- Product number
- L04950
- Product name
- 4-(Methylthio)aniline, 98%
- Packaging
- 5g
- Price
- $34.65
- Updated
- 2024/03/01
- Product number
- L04950
- Product name
- 4-(Methylthio)aniline, 98%
- Packaging
- 25g
- Price
- $139.65
- Updated
- 2024/03/01
4-(Methylmercapto)aniline Chemical Properties,Usage,Production
Chemical Properties
clear orange to brown-red liquid
Definition
ChEBI: 4-(methylthio) aniline is an aryl sulfide.
Synthesis Reference(s)
Tetrahedron Letters, 35, p. 7867, 1994 DOI: 10.1016/0040-4039(94)80139-8
Safety Profile
Moderately toxic by ingestion.When heated to decomposition it emits toxic vapors ofNOx and SOx.
Purification Methods
Purify the aniline by fractional distillation in an inert atmosphere. The hydrochloride has m 242-246o (from aqueous EtOH/HCl). The sulfone has m 137o (from H2O), pK2 5 1.48, and the sulfone hydrochloride has m 260-261o (from aqueous EtOH/HCl). [Lumbroso & Passerini Bull Soc Chim Fr 311 1957, Mangini & Passerini J Chem Soc 4954 1956, Beilstein 13 H 533, 13 II 297, 13 IV 1221.]
4-(Methylmercapto)aniline Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-(Methylmercapto)aniline manufacturers
- Product
- 4-(Methylmercapto)aniline 104-96-1
- Price
- US $200.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 5000KG
- Release date
- 2023-03-03
- Product
- 4-(Methylmercapto)aniline 104-96-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- 4-(Methylmercapto)aniline 104-96-1
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11