ChemicalBook > CAS DataBase List > 4-(Methylmercapto)aniline

4-(Methylmercapto)aniline

Product Name
4-(Methylmercapto)aniline
CAS No.
104-96-1
Chemical Name
4-(Methylmercapto)aniline
Synonyms
4-(METHYLTHIO)ANILINE;AKOS 91153;P-THIOANISIDINE;P-AMINOTHIOANISOLE;4-AMINOTHIOANISOLE;TIMTEC-BB SBB006658;p-Thiomethoxyaniline;4-(Methylmercapto)an;p-(methylthio)-anilin;P-(METHYLTHIO)ANILINE
CBNumber
CB9685172
Molecular Formula
C7H9NS
Formula Weight
139.22
MOL File
104-96-1.mol
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4-(Methylmercapto)aniline Property

Melting point:
156-158 °C
Boiling point:
272-273 °C(lit.)
Density 
1.119 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.639(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Liquid
pka
4.35(at 25℃)
color 
Clear orange to brown-red
Sensitive 
Stench
BRN 
774506
InChI
InChI=1S/C7H9NS/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
InChIKey
YKFROQCFVXOUPW-UHFFFAOYSA-N
SMILES
C1(N)=CC=C(SC)C=C1
CAS DataBase Reference
104-96-1(CAS DataBase Reference)
NIST Chemistry Reference
4-Methylmercaptoaniline(104-96-1)
EPA Substance Registry System
Benzenamine, 4-(methylthio)- (104-96-1)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36-37/39
RIDADR 
2810
WGK Germany 
3
RTECS 
BY6302000
F 
2-8-10-13
Hazard Note 
Irritant/Stench
TSCA 
T
HazardClass 
IRRITANT, STENCH
HazardClass 
6.1
PackingGroup 
III
HS Code 
29309090
Toxicity
LD50 orl-qal: 562 mg/kg AECTCV 12,355,83
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
M54503
Product name
4-(Methylthio)aniline
Purity
98%
Packaging
5g
Price
$32.2
Updated
2025/07/31
Sigma-Aldrich
Product number
M54503
Product name
4-(Methylthio)aniline
Purity
98%
Packaging
25g
Price
$92.9
Updated
2025/07/31
TCI Chemical
Product number
M1674
Product name
4-(Methylthio)aniline
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$154
Updated
2025/07/31
TRC
Product number
M725693
Product name
4-(Methylthio)aniline
Packaging
1g
Price
$45
Updated
2021/12/16
Apolloscientific
Product number
OR0773
Product name
4-(Methylthio)aniline
Purity
97%
Packaging
5g
Price
$57
Updated
2021/12/16
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4-(Methylmercapto)aniline Chemical Properties,Usage,Production

Chemical Properties

clear orange to brown-red liquid

Definition

ChEBI: 4-(methylthio) aniline is an aryl sulfide.

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 7867, 1994 DOI: 10.1016/0040-4039(94)80139-8

Safety Profile

Moderately toxic by ingestion.When heated to decomposition it emits toxic vapors ofNOx and SOx.

Purification Methods

Purify the aniline by fractional distillation in an inert atmosphere. The hydrochloride has m 242-246o (from aqueous EtOH/HCl). The sulfone has m 137o (from H2O), pK2 5 1.48, and the sulfone hydrochloride has m 260-261o (from aqueous EtOH/HCl). [Lumbroso & Passerini Bull Soc Chim Fr 311 1957, Mangini & Passerini J Chem Soc 4954 1956, Beilstein 13 H 533, 13 II 297, 13 IV 1221.]

4-(Methylmercapto)aniline Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-(Methylmercapto)aniline manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
4-(Methylmercapto)aniline 104-96-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%min
Supply Ability
1000kgs
Release date
2025-07-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-(Methylmercapto)aniline 104-96-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
4-(Methylmercapto)aniline 104-96-1
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

104-96-1, 4-(Methylmercapto)anilineRelated Search:

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