ETHYL 2-CYANO-3-METHYLCROTONATE

Product Name: ETHYL 2-CYANO-3-METHYLCROTONATE
CAS No.: 759-58-0
Chemical Name: ETHYL 2-CYANO-3-METHYLCROTONATE
Synonyms: TIMTEC-BB SBB007715;ETHYL 2-CYANO-3-METHYLCROTONATE;Ethyl 2-cyano-3-methylbutanoate;ETHYL 2-CYANO-3-METHYL-2-BUTENOATE;Ethyl isopropylidene(cyano)acetate;Ethyl 2-cyano-3-methyl-2-butanoate;Ethyl 2-cyano-3-methylbut-2-enoate;Ethyl 2-cyano-3-methyl-2-butenoate,98%;Ethyl 2-cyano-3-methyl-2-butenoate,97%;2-cyano-3-methylcrotonic acid ethyl ester
CBNumber: CB9688719
Molecular Formula: C8H11NO2
Formula Weight: 153.18
MOL File: 759-58-0.mol

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ETHYL 2-CYANO-3-METHYLCROTONATE Property

Melting point:: ca 20℃
Boiling point:: 98-99 °C/1 mmHg (lit.)
Density: 1.014 g/mL at 25 °C (lit.)
refractive index: n20/D 1.464(lit.)
Flash point:: 224 °F
BRN: 507839
InChI: 1S/C8H11NO2/c1-4-11-8(10)7(5-9)6(2)3/h4H2,1-3H3
InChIKey: PZMDAADKKAXROL-UHFFFAOYSA-N
SMILES: CCOC(=O)\C(C#N)=C(\C)C

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-37/39
RIDADR: 3276
WGK Germany: 3
HazardClass: 6.1
PackingGroup: III
HS Code: 29269095
Storage Class: 10 - Combustible liquids
Hazard Classifications: Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 310581
Product name: Ethyl 2-cyano-3-methyl-2-butenoate
Purity: 97%
Packaging: 5g
Price: $63.9
Updated: 2023/01/07

TRC

Product number: E898163
Product name: Ethyl2-Cyano-3-methylbut-2-enoate
Packaging: 1g
Price: $110
Updated: 2021/12/16

Matrix Scientific

Product number: 058941
Product name: 2-Cyano-3-methyl-but-2-enoic acid ethyl ester
Purity: 95+%
Packaging: 10g
Price: $284
Updated: 2021/12/16

AK Scientific

Product number: 9324AE
Product name: Ethyl2-cyano-3-methylcrotonate
Packaging: 5g
Price: $98
Updated: 2021/12/16

AK Scientific

Product number: 9324AE
Product name: Ethyl2-cyano-3-methylcrotonate
Packaging: 1g
Price: $34
Updated: 2021/12/16

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ETHYL 2-CYANO-3-METHYLCROTONATE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to slightly yellow liquid

Uses

Ethyl 2-cyano-3-methyl-2-butenoate, a highly activated acceptor, undergoes the phospha-Michael reaction upon trituration of the reagents at room temperature.

Synthesis Reference(s)

Journal of the American Chemical Society, 71, p. 3418, 1949 DOI: 10.1021/ja01178a044

General Description

Ethyl 2-cyano-3-methyl-2-butenoate, a highly activated acceptor, undergoes the phospha-Michael reaction upon trituration of the reagents at room temperature.

ETHYL 2-CYANO-3-METHYLCROTONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL 2-CYANO-3-METHYLCROTONATE Suppliers

Belgium 1 China 52 Germany 2 India 1 Japan 1 Switzerland 1 United Kingdom 5 United States 11 Global 74

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759-58-0, ETHYL 2-CYANO-3-METHYLCROTONATERelated Search:

ETHYL 2-CYANO-3-METHYLCROTONATE Ethyl 2-cyano-3,3-diphenylacrylate Octocrylene ETHYL CROTONATE ETHYL 2-(1-BENZYL-4-PIPERIDINYLIDENE)-2-CYANOACETATE ETHYL 2-CYANO-3-PHENYL-2-BUTENOATE CYANO-CYCLOHEXYLIDENE-ACETIC ACID ETHYL ESTER TIMTEC-BB SBB000822 DIETHYL DICYANOFUMARATE, 97 CYANO-[2-ETHYL-2-METHYL-TETRAHYDRO-PYRAN-(4E)-YLIDENE]-ACETIC ACID ETHYL ESTER CYANO-[1,2,5-TRIMETHYL-PIPERIDIN-(4Z)-YLIDENE]-ACETIC ACID ETHYL ESTER CYANO-[2,2-DIMETHYL-TETRAHYDRO-PYRAN-(4Z)-YLIDENE]-ACETIC ACID ETHYL ESTER ETHYL 2-NITRILO-2-(2-OXOINDOLIN-3-YLIDENE)ACETATE ETHYL 2-CYANO-2-CYCLOHEPTYLIDENACETATE ETHYL 2-CYANO-3-(2-METHOXYPHENYL)BUT-2-ENOATE ETHYL 2-(1-BENZYLHEXAHYDROPYRIDINIUM-4-YLIDEN)-2-CYANOACETATE CHLORIDE ethyl (1-benzyl-2-oxo-1,2-dihydro-3H-indol-3-ylidene)(cyano)acetate ETHYL 2-CYANO-3,4-DIMETHYL-2-PENTENOATE

Crotonic acid, 2-cyano-3-methyl-, ethyl ester

Ethyl isopropylidene(cyano)acetate

TIMTEC-BB SBB007715

ETHYL 2-CYANO-3-METHYLCROTONATE

ETHYL 2-CYANO-3-METHYL-2-BUTENOATE

Ethyl 2-cyano-3-methylbutanoate

2-cyano-3-methylcrotonic acid ethyl ester

Ethyl 2-cyano-3-methyl-2-butanoate

2-Cyano-3-methyl-2-butenoic acid ethyl ester

Ethyl 2-cyano-3-methyl-2-butenoate,97%

Ethyl 2-cyano-3-methyl-2-butenoate,98%

Ethyl 2-cyano-3-methylbut-2-enoate

2-Cyano-3-methyl-but-2-enoic acid ethyl ester

2-Butenoic acid, 2-cyano-3-methyl-, ethyl ester

759-58-0

CH32CCCNCO2C2H5

C8 to C9

Carbonyl Compounds

Building Blocks

Esters

Organic Building Blocks

Small molecule

C8 to C9

Carbonyl Compounds

Esters