ETHYL CROTONATE
- Product Name
- ETHYL CROTONATE
- CAS No.
- 10544-63-5
- Chemical Name
- ETHYL CROTONATE
- Synonyms
- FEMA 3486;Ethylcrotonat;Ethyl 2-butenoate;EthylcrotonateFCC;ETHYL T2 BUTENOATE;Ethyl but-2-enoate;RARECHEM AL BI 0145;ETHYLALPHA-CROTONATE;ETHYL TRANS-CROTONATE;TRANS-ETHYL CROTONATE
- CBNumber
- CB2241197
- Molecular Formula
- C6H10O2
- Formula Weight
- 114.14
- MOL File
- 10544-63-5.mol
ETHYL CROTONATE Property
- Melting point:
- 37.22°C (estimate)
- Boiling point:
- 142-143 °C(lit.)
- Density
- 0.918 g/mL at 25 °C(lit.)
- vapor density
- 3.9 (vs air)
- refractive index
- n20/D 1.424(lit.)
- FEMA
- 3486 | ETHYL TRANS-2-BUTENOATE
- Flash point:
- 36 °F
- storage temp.
- Flammables area
- form
- Liquid
- color
- Clear colorless
- Odor
- at 10.00 % in dipropylene glycol. pungent fruity acrid ester
- Odor Type
- fermented
- JECFA Number
- 1806
- LogP
- 1.806 (est)
- EPA Substance Registry System
- 2-Butenoic acid, ethyl ester (10544-63-5)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-34
- Safety Statements
- 16-26-36/37/39-45
- RIDADR
- UN 1862 3/PG 2
- WGK Germany
- 2
- RTECS
- GQ3500000
- HS Code
- 29161900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C818790
- Product name
- CrotonicAcidEthylEster
- Packaging
- 1g
- Price
- $160
- Updated
- 2021/12/16
- Product number
- JK282448
- Product name
- Ethyl Crotonate
- Purity
- 98%
- Packaging
- 5g
- Price
- $16
- Updated
- 2021/12/16
- Product number
- JK282448
- Product name
- Ethyl Crotonate
- Purity
- 98%
- Packaging
- 25g
- Price
- $34
- Updated
- 2021/12/16
- Product number
- JK282448
- Product name
- Ethyl Crotonate
- Purity
- 98%
- Packaging
- 100g
- Price
- $113
- Updated
- 2021/12/16
ETHYL CROTONATE Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Chemical Properties
Ethyl crotonate has a powerful, sour, caramellic-fruity odor.
Occurrence
Reported found in Fragaria vesca. Also reported found in guava fruit, guava peel, pineapple, white wine, yellow passion fruit, fresh mango, naranjilla fruit, mussel, loganberry, apple, papaya, concord grape, strawberry, rum, cocoa, plum, kiwifruit and other natural sources.
Uses
Crotonic Acid Ethyl Ester, is an intermediate for the preparation of various pharmaceutical compounds. It can be used for the synthesis of (+)-trans-Trikentrin A.
Definition
ChEBI: Ethyl crotonate is a fatty acid ester.
Preparation
By esterification of crotonic acid with ethyl alcohol in the presence of concentrated H2SO4.
Taste threshold values
Taste characteristics at 10 ppm: rum, cognac and pungent with caramellic and fruity nuances.
Synthesis Reference(s)
Journal of the American Chemical Society, 112, p. 2716, 1990 DOI: 10.1021/ja00163a038
Synthetic Communications, 14, p. 701, 1984 DOI: 10.1080/00397918408059583
General Description
A clear colorless liquid with a pungent odor. Flash point 36°F. Less dense than water and insoluble in water. Vapors heavier than air.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
ETHYL CROTONATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health Hazard
May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Profile
Slightly toxic by ingestion. Corrosive. An eye irritant and lachrymator. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
ETHYL CROTONATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ETHYL CROTONATE manufacturers
- Product
- ETHYL CROTONATE 10544-63-5
- Price
- US $6.00/KG
- Min. Order
- 2KG
- Purity
- 98%
- Supply Ability
- 1KG,50KG,100KG
- Release date
- 2019-09-03