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trans-1,4-Dichloro-2-butene

Product Name
trans-1,4-Dichloro-2-butene
CAS No.
110-57-6
Chemical Name
trans-1,4-Dichloro-2-butene
Synonyms
tri-1,4-Dichloro-2-b;1,4-Dichlorobutene-2;1,4-DICHLORO-2-BUTENE;2-BUTYLENE DICHLORIDE;4-dichloro-(e)-2-buten;1,4-DICHLORO-2-BUTYLENE;4-dichloro-trans-2-buten;trans-1,4-dichlorobutene;trans-1,4-Dichlor-2-buten;(E)-1,4-dichlorobut-2-ene
CBNumber
CB9705137
Molecular Formula
C4H6Cl2
Formula Weight
125
MOL File
110-57-6.mol
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trans-1,4-Dichloro-2-butene Property

Melting point:
1-3 °C(lit.)
Boiling point:
74-76 °C40 mm Hg(lit.)
Density 
1.183 g/mL at 25 °C(lit.)
vapor pressure 
10 mm Hg ( 20 °C)
refractive index 
n20/D 1.488(lit.)
Flash point:
129 °F
storage temp. 
2-8°C
solubility 
Chloroform, Ethyl Acetate
form 
Oil
color 
Clear Colourless to Light Yellow
BRN 
1719693
InChIKey
FQDIANVAWVHZIR-OWOJBTEDSA-N
CAS DataBase Reference
110-57-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Butene, 1,4-dichloro-, (E)-(110-57-6)
IARC
3 (Vol. 15, Sup 7, 71) 1999
EPA Substance Registry System
trans-1,4-Dichloro-2-butene (110-57-6)
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Safety

Hazard Codes 
T+,T,F,N
Risk Statements 
10-21-25-26-34-39/23/24/25-23/24/25-11-50/53-45-24/25
Safety Statements 
53-23-26-36/37/39-45-36/37-99-61-60-16
RIDADR 
UN 3390 6.1/PG 1
WGK Germany 
3
RTECS 
EM4903000
8-21
HazardClass 
6.1(a)
PackingGroup 
II
HS Code 
29032990
Hazardous Substances Data
110-57-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
324515
Product name
trans-1,4-Dichloro-2-butene
Purity
98%
Packaging
5g
Price
$65.8
Updated
2024/03/01
Sigma-Aldrich
Product number
324515
Product name
trans-1,4-Dichloro-2-butene
Purity
98%
Packaging
25g
Price
$234
Updated
2024/03/01
Sigma-Aldrich
Product number
215082
Product name
trans-1,4-Dichloro-2-butene
Purity
technical grade, 85%, remainder predominantly
Packaging
25g
Price
$62.4
Updated
2024/03/01
TRC
Product number
D432340
Product name
trans1,4-Dichloro-2-butene
Packaging
25g
Price
$105
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
39806
Product name
trans1,4-Dichloro-2-butene
Packaging
25g
Price
$675
Updated
2021/12/16
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trans-1,4-Dichloro-2-butene Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Chemical Properties

The 1,4-dichloro-2-butenes are colorless liquids. Some have a distinct odor. (cis-isomer)

Uses

1,4-Dichloro-2-butene is used in the synthesis of anthraquinones used in the asymmetric dihydroxylation of olefins. Also used to prepare arylcarboxamides used as novel dopamine receptor antagonists.

Definition

ChEBI: Trans-1,4-Dichlorobutene is an organochlorine compound.

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 2118, 1951 DOI: 10.1021/ja01149a061
The Journal of Organic Chemistry, 36, p. 2088, 1971 DOI: 10.1021/jo00814a013

General Description

Colorless liquid with a distinct odor. An intermediate for hexamethylenediamine and chloroprene.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

trans-1,4-Dichloro-2-butene will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. [EPA, 1998].

Health Hazard

(Non-Specific -- Dichlorobutene) Liquid and vapors from the material are highly corrosive and may damage skin, eyes, lungs, and internal organs.

Fire Hazard

The material will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds.

Potential Exposure

DC occurs as a by-product in chloroprene manufacture and may be used as a chemical intermediate

Shipping

UN3384 Toxic by inhalation liquid, flammable, n. o.s. with an LC50 ≦ 1000 ml/m3 and saturated vapor concentration ≧to 10 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone B. UN2920 Corrosive liquids, flammable, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, 3-Flammable liquid. The code “D” identifies proper shipping names which are appropriate for describing materials for domestic transportation but may be inappropriate for international transportation under the provisions of international regulations, e.g., IMO, ICAO). An alternate proper shipping name may be selected when either domestic or international transportation is involved

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. (cis-isomer): Reacts slowly with water forming hydrogen chloride. Attacks metals and may form other, more dangerous materials; attacks some plastics.

Waste Disposal

High-temperature incineration with hydrochloric acid scrubbing. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

trans-1,4-Dichloro-2-butene Preparation Products And Raw materials

Raw materials

Preparation Products

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trans-1,4-Dichloro-2-butene Suppliers

Hubei zhonglong Kangsheng Fine Chemical Co., Ltd
Tel
027-027-83850178 18162590268
Fax
027-83850178
Email
1984393783@qq.com
Country
China
ProdList
3876
Advantage
58
Shandong Hongyuan Chemical Technology Co., LTD
Tel
13561560789
Email
xinxiaoxiao2008@126.com
Country
China
ProdList
320
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7508
Advantage
55
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9816
Advantage
59
Beijing Lunarsun Pharmaceutical Co.,LTD.
Tel
86-10-64911848-8020.8010
Fax
86-10-64946614
Email
sales@lunarsun.com.cn
Country
China
ProdList
95
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32344
Advantage
50
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View Lastest Price from trans-1,4-Dichloro-2-butene manufacturers

Henan Fengda Chemical Co., Ltd
Product
trans-1,4-Dichlorobutene 110-57-6
Price
US $9.00-0.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-23
Hebei Mingeng Biotechnology Co., Ltd
Product
trans-1,4-Dichlorobutene 110-57-6
Price
US $150.00/g
Min. Order
10g
Purity
>99%
Supply Ability
10 t
Release date
2021-11-22
Henan Aochuang Chemical Co.,Ltd.
Product
trans-1,4-Dichloro-2-butene 110-57-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-13

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