trans-1,4-Dichloro-2-butene

Product Name: trans-1,4-Dichloro-2-butene
CAS No.: 110-57-6
Chemical Name: trans-1,4-Dichloro-2-butene
Synonyms: tri-1,4-Dichloro-2-b;1,4-Dichlorobutene-2;1,4-DICHLORO-2-BUTENE;2-BUTYLENE DICHLORIDE;4-dichloro-(e)-2-buten;1,4-DICHLORO-2-BUTYLENE;4-dichloro-trans-2-buten;trans-1,4-dichlorobutene;trans-1,4-Dichlor-2-buten;(E)-1,4-dichlorobut-2-ene
CBNumber: CB9705137
Molecular Formula: C4H6Cl2
Formula Weight: 125
MOL File: 110-57-6.mol

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trans-1,4-Dichloro-2-butene Property

Melting point:: 1-3 °C(lit.)
Boiling point:: 74-76 °C40 mm Hg(lit.)
Density: 1.183 g/mL at 25 °C(lit.)
vapor pressure: 10 mm Hg ( 20 °C)
refractive index: n20/D 1.488(lit.)
Flash point:: 129 °F
storage temp.: 2-8°C
solubility: Chloroform, Ethyl Acetate
form: Oil
color: Clear Colourless to Light Yellow
BRN: 1719693
InChIKey: FQDIANVAWVHZIR-OWOJBTEDSA-N
CAS DataBase Reference: 110-57-6(CAS DataBase Reference)
NIST Chemistry Reference: 2-Butene, 1,4-dichloro-, (E)-(110-57-6)
IARC: 3 (Vol. 15, Sup 7, 71) 1999
EPA Substance Registry System: trans-1,4-Dichloro-2-butene (110-57-6)

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Safety

Hazard Codes: T+,T,F,N
Risk Statements: 10-21-25-26-34-39/23/24/25-23/24/25-11-50/53-45-24/25
Safety Statements: 53-23-26-36/37/39-45-36/37-99-61-60-16
RIDADR: UN 3390 6.1/PG 1
WGK Germany: 3
RTECS: EM4903000
F: 8-21
HazardClass: 6.1(a)
PackingGroup: II
HS Code: 29032990
Hazardous Substances Data: 110-57-6(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 324515
Product name: trans-1,4-Dichloro-2-butene
Purity: 98%
Packaging: 5g
Price: $65.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 324515
Product name: trans-1,4-Dichloro-2-butene
Purity: 98%
Packaging: 25g
Price: $234
Updated: 2024/03/01

Sigma-Aldrich

Product number: 215082
Product name: trans-1,4-Dichloro-2-butene
Purity: technical grade, 85%, remainder predominantly
Packaging: 25g
Price: $62.4
Updated: 2024/03/01

TRC

Product number: D432340
Product name: trans1,4-Dichloro-2-butene
Packaging: 25g
Price: $105
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 39806
Product name: trans1,4-Dichloro-2-butene
Packaging: 25g
Price: $675
Updated: 2021/12/16

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trans-1,4-Dichloro-2-butene Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Chemical Properties

The 1,4-dichloro-2-butenes are colorless liquids. Some have a distinct odor. (cis-isomer)

Uses

1,4-Dichloro-2-butene is used in the synthesis of anthraquinones used in the asymmetric dihydroxylation of olefins. Also used to prepare arylcarboxamides used as novel dopamine receptor antagonists.

Definition

ChEBI: Trans-1,4-Dichlorobutene is an organochlorine compound.

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 2118, 1951 DOI: 10.1021/ja01149a061
The Journal of Organic Chemistry, 36, p. 2088, 1971 DOI: 10.1021/jo00814a013

General Description

Colorless liquid with a distinct odor. An intermediate for hexamethylenediamine and chloroprene.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

trans-1,4-Dichloro-2-butene will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. [EPA, 1998].

Health Hazard

(Non-Specific -- Dichlorobutene) Liquid and vapors from the material are highly corrosive and may damage skin, eyes, lungs, and internal organs.

Fire Hazard

The material will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds.

Potential Exposure

DC occurs as a by-product in chloroprene manufacture and may be used as a chemical intermediate

Shipping

UN3384 Toxic by inhalation liquid, flammable, n. o.s. with an LC50 ≦ 1000 ml/m3 and saturated vapor concentration ≧to 10 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone B. UN2920 Corrosive liquids, flammable, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, 3-Flammable liquid. The code “D” identifies proper shipping names which are appropriate for describing materials for domestic transportation but may be inappropriate for international transportation under the provisions of international regulations, e.g., IMO, ICAO). An alternate proper shipping name may be selected when either domestic or international transportation is involved

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. (cis-isomer): Reacts slowly with water forming hydrogen chloride. Attacks metals and may form other, more dangerous materials; attacks some plastics.

Waste Disposal

High-temperature incineration with hydrochloric acid scrubbing. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

trans-1,4-Dichloro-2-butene Preparation Products And Raw materials

Raw materials

N-Bromosuccinimide 1-Hydroxybenzotriazole Ferric chloride Copper(I) chloride Pyridine Thionyl chloride 2-Butene-1,4-diol

Preparation Products

N,N,N',N'-TETRAMETHYL-2-BUTENE-1,4-DIAMINE

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trans-1,4-Dichloro-2-butene Suppliers

Belgium 1 China 149 Europe 3 France 1 Germany 4 India 2 Japan 1 Slovakia 1 Switzerland 2 United Kingdom 6 United States 25 Global 195

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View Lastest Price from trans-1,4-Dichloro-2-butene manufacturers

Henan Fengda Chemical Co., Ltd

Product: trans-1,4-Dichlorobutene 110-57-6
Price: US $9.00-0.90/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-23

Hebei Mingeng Biotechnology Co., Ltd

Product: trans-1,4-Dichlorobutene 110-57-6
Price: US $150.00/g
Min. Order: 10g
Purity: >99%
Supply Ability: 10 t
Release date: 2021-11-22

Henan Aochuang Chemical Co.,Ltd.

Product: trans-1,4-Dichloro-2-butene 110-57-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-10-13

110-57-6, trans-1,4-Dichloro-2-buteneRelated Search:

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trans-1,4-Dichloro-2-butene 110-57-6

110-57-6 trans-1,4-Dichloro-2-butene

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TRANS-1,4-DICHLORO-2-BUTENE 1X1ML MEOH 2 000UG/ML

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trans-1,4-Dichlorobuten-2-ene

trans-1,4-dichlorobutene

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trans-1,4-Dichloro-2-buteme

DICHLORO(TRANS-1,4-)-2-BUTENE

(E)-1,4-Dichloro-2-butene

1,4-DICHLORO-2-BUTENE

1,4-DICHLORO-2-BUTENE CIS AND TRANS

1,4-DICHLORO-2-BUTYLENE

(2E)-1,4-Dichloro-2-butene

1,4-Dichloro-(E)-2-butene

1,4-Dichlorobutene-2

1,4-Dichloro-trans-2-butene

2-Butene, 1,4-dichloro-, trans-

2-Butene,1,4-dichloro-,(2E)-

TRANS-1,4-DICHLORO-2-BUTENE

TRANS-1,4-DICHLORO-2-BUTYLENE

trans-1,4-Dichlorobutene-2

2-BUTYLENE DICHLORIDE

trans-1,4-Dichloro-2-butene &gt

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trans-1,4-Dichlorobut-2-ene - Hazardous material, cannot be shipped outside of the UK

rans-1,4-Dichloro-2-butene

110-57-6

761-41-0

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