9-(Chloromethyl)anthracene

Product Name: 9-(Chloromethyl)anthracene
CAS No.: 24463-19-2
Chemical Name: 9-(Chloromethyl)anthracene
Synonyms: icr448;ICR 448;9-Chlormethyl-anthracen;9-Chloromethyanthracene;9-chloromethyl-anthracen;9-CHLOROMETHYLANTHRACENE;9-(choromethyl)anthracene;9-(chloroMethyl)antracene;(9-Anthrylmethyl) chloride;(9-Anthryl)methyl chloride
CBNumber: CB9740578
Molecular Formula: C15H11Cl
Formula Weight: 226.7
MOL File: 24463-19-2.mol

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9-(Chloromethyl)anthracene Property

Melting point:: 138-140 °C (lit.)
Boiling point:: 294.66°C (rough estimate)
Density: 1.1510 (rough estimate)
refractive index: 1.6281 (estimate)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
solubility: chloroform: soluble
form: Powder
color: Yellow
Water Solubility: Soluble in chloroform. Insoluble in water.
Sensitive: Light Sensitive
BRN: 1873394
CAS DataBase Reference: 24463-19-2(CAS DataBase Reference)
NIST Chemistry Reference: 9-(Chloromethyl)anthracene(24463-19-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
RTECS: CA9600000
F: 19
HazardClass: 8
PackingGroup: III
HS Code: 29039990
Toxicity: mouse,LDLo,intravenous,2267ug/kg (2.267mg/kg),Cancer Research. Vol. 36, Pg. 2423, 1976.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H318Causes serious eye damage

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: A5502
Product name: 9-Chloromethylanthracene [for HPLC Labeling]
Purity: >97.0%(T)
Packaging: 1g
Price: $29
Updated: 2024/03/01

TCI Chemical

Product number: A5502
Product name: 9-Chloromethylanthracene [for HPLC Labeling]
Purity: >97.0%(T)
Packaging: 5g
Price: $87
Updated: 2024/03/01

Alfa Aesar

Product number: A13579
Product name: 9-(Chloromethyl)anthracene, 98+%
Packaging: 5g
Price: $145
Updated: 2024/03/01

Alfa Aesar

Product number: A13579
Product name: 9-(Chloromethyl)anthracene, 98+%
Packaging: 25g
Price: $634
Updated: 2024/03/01

TCI Chemical

Product number: C1046
Product name: 9-Chloromethylanthracene
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $26
Updated: 2024/03/01

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9-(Chloromethyl)anthracene Chemical Properties,Usage,Production

Chemical Properties

YELLOW POWDER

Uses

9-(Chloromethyl)anthracene is used as a blocking group reagent used for carboxylic acids, phenols, mercaptans and thiophenols. It is a derivatizing agent for carboxylic acids giving esters with enhanced UV and fluorescence detection in HPLC.

Application

9-Anthracenylmethyl Chloride is a derivative of Anthracene which is an important source of dyestuffs. It is a reagent for the protection of carboxylic acids, alcohols, phenols and thiols as their 9-anthrylmethyl derivatives, which are stable to mild acid or base, but specifically cleaved by NaSMe.

Reactions

Lepidopterene, a tetrabenzotetracyclotetradecatetraene, was first synthesized by reaction of 9-(chloromethyl)anthracene with methylmagnesium iodide. Through this methodology, lepidopterene and 1,2-bis(9-anthracenyl)ethane were obtained in 35% and 30% yield, respectively.

An easy synthesis of lepidopterene from 9-chloromethylanthracene

Purification Methods

If it is free from OH in the IR then recrystallisation from hexane/*C6H6 or *C6H6 (as needles). If OH is present, then some solvolysis has occurred. In this case treat 8.5g of it with SOCl2 (4.8g) in dioxane (60mL) and reflux for 5hours, then evaporate to dryness and wash the residue with cold *C6H6 and recrystallise it. With KI/Me2CO it forms the iodomethyl derivative. [Fierens et al. Helv Chim Acta 38 2009 1955, Hunter et al. J Org Chem 21 1512 1956, Beilstein 5 III 3152, 5 IV 2313.]

9-(Chloromethyl)anthracene Preparation Products And Raw materials

Raw materials

9-Anthraldehyde Sodium borohydride 1,4-Dioxane Tetrahydrofuran Thionyl chloride

Preparation Products

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View Lastest Price from 9-(Chloromethyl)anthracene manufacturers

Nanjing Kaitian Chemical Co., LTD

Product: 9-(Chloromethyl)anthracene 24463-19-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 95%
Supply Ability: 300kg
Release date: 2022-12-06

Career Henan Chemical Co

Product: 9-(Chloromethyl)anthracene 24463-19-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2019-08-29

24463-19-2, 9-(Chloromethyl)anthraceneRelated Search:

4-(Chloromethyl)benzoic acid DIMETHYLTHEXYLSILYL CHLORIDE tert-Butyldimethylsilyl chloride Chloromethane Anthracene Chloromethyl silane Benzyl chloride Vinylbenzyl chloride Chloromethyl methyl ether 9,10-Bis(chloromethyl)anthracene 6-CHLOROMETHYLBENZO(A)PYRENE 9-ANTHRACENECARBONYL CHLORIDE 7-chloromethyl-12-methylbenz(a)anthracene ALPHA-CHLORO-9-ANTHRALDOXIME 9-(Chloromethyl)anthracene

9-(choromethyl)anthracene

9-CHLOROMETHYL-ANTHRACENE, FOR FLUOR-ESC ENCE

9-(CHLOROMETHYL)ANTHRACENE, 98+%

(9-Anthryl)methyl chloride

(9-Anthrylmethyl) chloride

9-(chloroMethyl)antracene

9-(ChloroMethyl)anthracene, 98+% 10GR

9-(ChloroMethyl)anthracene, 98+% 2.5GR

9-(Chloromethyl)anthracene BioReagent, suitable for fluorescence, >=97.0% (AT)

9-CHLOROMETHYLANTHRACENE, FOR HPLC LABELING

9-anthracenylmethylchloride

9-Chlormethyl-anthracen

9-Chloromethyanthracene

9-chloromethyl-anthracen

Anthracene, 9-(chloromethyl)-

ICR 448

icr448

9-CHLOROMETHYLANTHRACENE

9-Chloromethylanthracene &gt

9-Chloromethylanthracene [for HPLC Labeling]&gt

9-Chloromethylanthracene, 98%, reagent grade

24463-19-2

24463-98-3

463-19-2

C15H11Cl

BENZYL HALIDE

HPLC Labeling Reagents

Fluorescence Detection (HPLC Labeling Reagents)

Carboxyl Group Labeling Reagents for HPLC

UV Detection (HPLC Labeling Reagents)

Anthracenes

Carboxyl Group Labeling Reagents for Fluorescence HPLC

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BioChemical

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Aromatic Hydrocarbons (substituted) & Derivatives

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Anthracenes

Carboxyl Group Labeling Reagents for Fluorescence HPLC

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