ChemicalBook > CAS DataBase List > trans-Methyl crotonate
trans-Methyl crotonate
Synthesis- Product Name
- trans-Methyl crotonate
- CAS No.
- 623-43-8
- Chemical Name
- trans-Methyl crotonate
- Synonyms
- METHYICROTONATE;METHYL CROTONATE;Methyl-2-Crotonate;Methyl E-crotonate;MethylCrotonate>METHYL BUT-2-ENOATE;Methylcrotonate,98%;Methyl-α-crotonate;Crotonic acid methyl;Methyl crotonate 98%
- CBNumber
- CB9745331
- Molecular Formula
- C5H8O2
- Formula Weight
- 100.12
- MOL File
- 623-43-8.mol
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trans-Methyl crotonate Property
- Melting point:
- -42°C
- Boiling point:
- 118-120 °C (lit.)
- Density
- 0.944 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.423(lit.)
- Flash point:
- 40 °F
- storage temp.
- Flammables area
- form
- Liquid
- color
- Clear colorless
- Odor
- at 1.00 % in dipropylene glycol. sharp green fruity
- Odor Type
- green
- Water Solubility
- IMMISCIBLE
- Merck
- 14,2597
- BRN
- 1720292
- InChI
- InChI=1S/C5H8O2/c1-3-4-5(6)7-2/h3-4H,1-2H3/b4-3+
- InChIKey
- MCVVUJPXSBQTRZ-ONEGZZNKSA-N
- SMILES
- C(OC)(=O)/C=C/C
- LogP
- 1.316 (est)
- CAS DataBase Reference
- 623-43-8(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Butenoic acid, methyl ester, (E)-(623-43-8)
- EPA Substance Registry System
- Methyl trans-crotonate (623-43-8)
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Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 16-26-36-9-33
- RIDADR
- UN 3272 3/PG 2
- WGK Germany
- 2
- RTECS
- GQ5710000
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29161980
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H319Causes serious eye irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 139459
- Product name
- Methyl crotonate
- Purity
- 98%
- Packaging
- 5ml
- Price
- $31
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 139459
- Product name
- Methyl crotonate
- Purity
- 98%
- Packaging
- 100ml
- Price
- $83.9
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C0419
- Product name
- Methyl Crotonate
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $21
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C0419
- Product name
- Methyl Crotonate
- Purity
- >98.0%(GC)
- Packaging
- 100mL
- Price
- $43
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A15363
- Product name
- Methyl crotonate, 98%
- Packaging
- 100g
- Price
- $35.65
- Updated
- 2024/03/01
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trans-Methyl crotonate Chemical Properties,Usage,Production
Synthesis
Trans-Methyl crotonate is obtained by esterification of crotonic acid and methanol. The reaction solution prepared by 800g of crotonic acid, 1L of methanol, 130g of sulfuric acid and 300ml of carbon tetrachloride was heated on a water bath, and carbon tetrachloride was recovered after dehydration and esterification to obtain a crude product of methyl crotonate. Then, the unreacted crotonic acid in the crude product is washed with water, washed with 5% sodium carbonate, and purified by vacuum distillation to obtain the finished product.
Chemical Properties
CLEAR COLOURLESS LIQUID
Uses
Methyl crotonate was used to investigate chemo selectivity in the reaction between methyl crotonate and benzyl amine catalyzed by lipase B from Candida Antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2).
Synthesis Reference(s)
Tetrahedron Letters, 14, p. 2967, 1973 DOI: 10.1016/S0040-4039(01)96294-X
General Description
Methyl crotonate undergoes vinylogous aldol reaction with enolizable aldehydes in the presence of aluminum tris(2,6-di-2-naphthylphenoxide).
trans-Methyl crotonate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from trans-Methyl crotonate manufacturers
Career Henan Chemical Co
- Product
- trans-Methyl crotonate 623-43-8
- Price
- US $7.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2018-12-21
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