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METHYL 3-BUTENOATE

Product Name
METHYL 3-BUTENOATE
CAS No.
3724-55-8
Chemical Name
METHYL 3-BUTENOATE
Synonyms
methyl but-3-enoate;but-3-enoic acid methyl ester;CH2=CHCH2C(O)OCH3;METHYL 3-BUTENOATE;METHYL VINYLACETATE;Methyl 3-butenoate 95%;3-butenoicacid,methylester
CBNumber
CB5734904
Molecular Formula
C5H8O2
Formula Weight
100.12
MOL File
3724-55-8.mol
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METHYL 3-BUTENOATE Property

Melting point:
-78.42°C (estimate)
Boiling point:
112 °C (lit.)
Density 
0.939 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.409(lit.)
Flash point:
60 °F
BRN 
1741732
InChIKey
GITITJADGZYSRL-UHFFFAOYSA-N
LogP
0.839 (est)
NIST Chemistry Reference
Methyl 3-butenoate(3724-55-8)
EPA Substance Registry System
3-Butenoic acid, methyl ester (3724-55-8)
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Safety

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
16
RIDADR 
UN 3272 3/PG 2
WGK Germany 
3
HazardClass 
3.1
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
384267
Product name
Methyl 3-butenoate
Purity
95%
Packaging
1g
Price
$75.6
Updated
2024/03/01
Sigma-Aldrich
Product number
384267
Product name
Methyl 3-butenoate
Purity
95%
Packaging
5g
Price
$173.6
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0069402
Product name
METHYL 3-BUTENOATE
Purity
95.00%
Packaging
1G
Price
$702.52
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0069402
Product name
METHYL 3-BUTENOATE
Purity
95.00%
Packaging
5G
Price
$1201.87
Updated
2021/12/16
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METHYL 3-BUTENOATE Chemical Properties,Usage,Production

Uses

Methyl 3-butenoate may be employed for the synthesis of dipeptide olefin isosteres using intermolecular olefin cross-metathesis.

Synthesis Reference(s)

Journal of the American Chemical Society, 99, p. 5184, 1977 DOI: 10.1021/ja00457a052
Tetrahedron Letters, 14, p. 2433, 1973 DOI: 10.1016/S0040-4039(01)96239-2

General Description

Methyl 3-butenoate is an olefin ester. It is reported to undergo Iron carbonyl-promoted isomerization to afford α, β-unsaturated esters. It is one of the reaction products formed during flash vacuum thermolysis of (?)-cocaine. The H2 and CH4 chemical ionization mass spectra of methyl 3-butenoate has been reported.

METHYL 3-BUTENOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-BUTENOATE Suppliers

China 79 India 1 Switzerland 1 United Kingdom 1 United States 8 USA 1 Global 91
Hangzhou Copiore Chemical Co., Ltd.
Tel
0571-56076030 13757145729
Fax
0571-56076030
Email
sales@copiore.com
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China
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Chengdu RunZeBenTu Chemical Co., Ltd
Tel
028-88469284 18000562381
Email
rzbtsj@163.com
Country
China
ProdList
9958
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56
Hangzhou Lordaerun Medical Technology Co., LTD
Tel
18968132030
Email
414725184@qq.com
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China
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142
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58
ZHEJIANG ZETIAN FINE CHEMICALS CO.,LTD
Tel
0571-0571-87322520/800182836 18305707819
Fax
QQ:3007632051
Email
sales@zetchem.com
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China
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Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-022-83946278 13820372920
Fax
022-83945176
Email
sales@creasyn.com
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China
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994
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BeiJing Hwrk Chemicals Limted
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0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
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China
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JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
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9984
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Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
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China
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
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3724-55-8, METHYL 3-BUTENOATERelated Search:

Octenyl succinic anhydride Methyl coumalate ISOOCTADECENYLSUCCINIC ANHYDRIDE 5-Carbethoxy-4,6-dimethyl-2-pyrone N-HEXADECENYLSUCCINIC ANHYDRIDE Dimethyl itaconate Itaconic anhydride Methyl isodehydroacetate TETRADECENYLSUCCINIC ANHYDRIDE DIMETHYL 3-METHYLGLUTACONATE 2-DECEN-1-YLSUCCINIC ANHYDRIDE 4-CARBETHOXY-3-METHYL-2-CYCLOHEXEN-1-ONE PENTAMETHYL CYCLOPENTADIENE-1,2,3,4,5-PENTACARBOXYLATE 3,6-DIHYDRO-4,6,6-TRIMETHYL-2H-PYRAN-2-ONE DIETHYL GLUTACONATE METHYL 2,5-DIHYDRO-2,5-DIMETHOXY-2-FURANCARBOXYLATE TETRAMETHYL 2,6-DIHYDROXYBICYCLO[3.3.1]NONA-2,6-DIENE-1,3,5,7-TETRACARBOXYLATE 4-CARBETHOXY-2-ETHYL-3-METHYL-2-CYCLOHEXEN-1-ONE

  • 3-butenoicacid,methylester
  • CH2=CHCH2C(O)OCH3
  • METHYL VINYLACETATE
  • METHYL 3-BUTENOATE
  • but-3-enoic acid methyl ester
  • methyl but-3-enoate
  • Methyl 3-butenoate 95%
  • 3724-55-8
  • 3724558
  • Organic Building Blocks
  • Esters
  • ESTER
  • Building Blocks
  • Carbonyl Compounds
  • C2 to C5