ChemicalBook > CAS DataBase List > METHYL 3-BUTENOATE
METHYL 3-BUTENOATE
- Product Name
- METHYL 3-BUTENOATE
- CAS No.
- 3724-55-8
- Chemical Name
- METHYL 3-BUTENOATE
- Synonyms
- methyl but-3-enoate;but-3-enoic acid methyl ester;CH2=CHCH2C(O)OCH3;METHYL 3-BUTENOATE;METHYL VINYLACETATE;Methyl 3-butenoate 95%;3-butenoicacid,methylester
- CBNumber
- CB5734904
- Molecular Formula
- C5H8O2
- Formula Weight
- 100.12
- MOL File
- 3724-55-8.mol
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METHYL 3-BUTENOATE Property
- Melting point:
- -78.42°C (estimate)
- Boiling point:
- 112 °C (lit.)
- Density
- 0.939 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.409(lit.)
- Flash point:
- 60 °F
- BRN
- 1741732
- InChIKey
- GITITJADGZYSRL-UHFFFAOYSA-N
- LogP
- 0.839 (est)
- NIST Chemistry Reference
- Methyl 3-butenoate(3724-55-8)
- EPA Substance Registry System
- 3-Butenoic acid, methyl ester (3724-55-8)
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 384267
- Product name
- Methyl 3-butenoate
- Purity
- 95%
- Packaging
- 1g
- Price
- $75.6
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 384267
- Product name
- Methyl 3-butenoate
- Purity
- 95%
- Packaging
- 5g
- Price
- $173.6
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- CHM0069402
- Product name
- METHYL 3-BUTENOATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $702.52
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM0069402
- Product name
- METHYL 3-BUTENOATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1201.87
- Updated
- 2021/12/16
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METHYL 3-BUTENOATE Chemical Properties,Usage,Production
Uses
Methyl 3-butenoate may be employed for the synthesis of dipeptide olefin isosteres using intermolecular olefin cross-metathesis.
Synthesis Reference(s)
Journal of the American Chemical Society, 99, p. 5184, 1977 DOI: 10.1021/ja00457a052
Tetrahedron Letters, 14, p. 2433, 1973 DOI: 10.1016/S0040-4039(01)96239-2
General Description
Methyl 3-butenoate is an olefin ester. It is reported to undergo Iron carbonyl-promoted isomerization to afford α, β-unsaturated esters. It is one of the reaction products formed during flash vacuum thermolysis of (?)-cocaine. The H2 and CH4 chemical ionization mass spectra of methyl 3-butenoate has been reported.
METHYL 3-BUTENOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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