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tert-Butyl acrylate

Product Name
tert-Butyl acrylate
CAS No.
1663-39-4
Chemical Name
tert-Butyl acrylate
Synonyms
TBA;T-BUTYL ACRYLATE;tert-Butyl prop-2-enoate;TERTIARY-BUTYL ACRYLATE;TERT-BUTYL ACRYLATE (TBA);TERT-BUTYL ACRYLATE;tert-butylpropenoate;Acrylic acid tert-butyl;TBA tert-Butyl acrylate;Propenoic acid tert-butyl
CBNumber
CB9766596
Molecular Formula
C7H12O2
Formula Weight
128.17
MOL File
1663-39-4.mol
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tert-Butyl acrylate Property

Melting point:
-69°C
Boiling point:
61-63 °C/60 mmHg (lit.)
Density 
0.875 g/mL at 25 °C (lit.)
vapor pressure 
20hPa at 23.4℃
refractive index 
n20/D 1.410(lit.)
Flash point:
63 °F
storage temp. 
Flammables area
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear
Water Solubility 
2 g/L
BRN 
1742329
LogP
2.32 at 25℃
CAS DataBase Reference
1663-39-4(CAS DataBase Reference)
NIST Chemistry Reference
Tert-butyl acrylate(1663-39-4)
EPA Substance Registry System
2-Propenoic acid, 1,1-dimethylethyl ester (1663-39-4)
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Safety

Hazard Codes 
F,Xn,N
Risk Statements 
11-20/21/22-37/38-43-52/53-51/53
Safety Statements 
16-25-37-61
RIDADR 
UN 1993 3/PG 2
WGK Germany 
2
10
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29161290
Hazardous Substances Data
1663-39-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H317May cause an allergic skin reaction

H331Toxic if inhaled

H335May cause respiratory irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
327182
Product name
tert-Butyl acrylate
Purity
contains 10-20 ppm monomethyl ether hydroquinone as inhibitor, 98%
Packaging
1l
Price
$142
Updated
2024/03/01
TCI Chemical
Product number
A1389
Product name
tert-Butyl Acrylate (stabilized with MEHQ)
Purity
>98.0%(GC)
Packaging
25mL
Price
$20
Updated
2024/03/01
TCI Chemical
Product number
A1389
Product name
tert-Butyl Acrylate (stabilized with MEHQ)
Purity
>98.0%(GC)
Packaging
500mL
Price
$48
Updated
2024/03/01
Alfa Aesar
Product number
L17169
Product name
tert-Butyl acrylate, 99%, stab. with 15ppm 4-methoxyphenol
Packaging
100ml
Price
$34.7
Updated
2024/03/01
Alfa Aesar
Product number
L17169
Product name
tert-Butyl acrylate, 99%, stab. with 15ppm 4-methoxyphenol
Packaging
500ml
Price
$66.5
Updated
2024/03/01
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tert-Butyl acrylate Chemical Properties,Usage,Production

Chemical Properties

clear liquid

Uses

Monomer for acrylic resins.

Uses

tert-Butyl acrylate is a monomer used in the production of poly(tert-butyl acrylate) polymers, poly(acrylic acid) polyelectrolyte brushes and 3-(3-methyl-but-3-enyloxy)-propionic acid tert-butyl ester. It is also used in paints, coatings, high polymer paper conditioner, nursing polymer products and carbonyl reforming polyolefin. Further, it serves as an important raw material in organic synthesis.

Uses

tert-Butyl acrylate is a monomer used to produce poly(tert-butyl acrylate) (PtBA) polymers and copolymers, and poly(acrylic acid) polyelectrolyte brushes. It undergoes radiation polymerization to form TBA-gels for radio-fluorogenic dose imaging applications. The monomer can be used to synthesize Poly(t-butyl acrylate). It may be used as a reactive diluent in a study.

Preparation

Acrylic acid, strongly acidic cation exchange resin, a polymerization inhibitor A, B polymerization inhibitor, liquefied isobutene was 320 parts by mass of the parts, 35 parts, 20 parts, 5 parts, 430 parts. After a dropping time of 3 hours, the esterification reaction temperature was maintained at 10 ° C. After the addition was completed, 10 ° C was under insulation, and thermal insulation was 7 hours. Quality copies obtained 450 parts of tert-butyl acrylate, and the yield was 99.7%.

Hazard

Toxic by ingestion and inhalation. Flammable, dangerous fire risk.

Flammability and Explosibility

Flammable

tert-Butyl acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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tert-Butyl acrylate Suppliers

Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81
Acros Organics (Part of Thermo Fisher Scientific )
Tel
--
Fax
--
Email
fo@acros.com
Country
Belgium
ProdList
3824
Advantage
58
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View Lastest Price from tert-Butyl acrylate manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
tert-Butyl acrylate 1663-39-4
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2024-08-26
Hebei Yanxi Chemical Co., Ltd.
Product
tert-Butyl acrylate 1663-39-4
Price
US $25.00-12.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-11-21
Hebei Chuanghai Biotechnology Co,.LTD
Product
tert-Butyl acrylate 1663-39-4
Price
US $10.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2024-08-21

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