(4-AMINO-3-METHOXYPHENYL)METHANOL

Product Name: (4-AMINO-3-METHOXYPHENYL)METHANOL
CAS No.: 148459-54-5
Chemical Name: (4-AMINO-3-METHOXYPHENYL)METHANOL
Synonyms: 4-Amino-3-methoxybenzyl Alcohol;(4-AMINO-3-METHOXYPHENYL)METHANOL;4-Amino-3-methoxy-benzenemethanol;BenzeneMethanol,4-aMino-3-Methoxy-;[4-Amino-3-(methyloxy)phenyl]methanol
CBNumber: CB9774616
Molecular Formula: C8H11NO2
Formula Weight: 153.18
MOL File: 148459-54-5.mol

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(4-AMINO-3-METHOXYPHENYL)METHANOL Property

Boiling point:: 312℃
Density: 1.182
Flash point:: 142℃
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
Appearance: Light brown to yellow Liquid
InChI: InChI=1S/C8H11NO2/c1-11-8-4-6(5-10)2-3-7(8)9/h2-4,10H,5,9H2,1H3
InChIKey: RVYSKGNWKIIUIF-UHFFFAOYSA-N
SMILES: C1(CO)=CC=C(N)C(OC)=C1

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Safety

HS Code: 2922500090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: A634810
Product name: (4-Amino-3-methoxyphenyl)methanol
Packaging: 1g
Price: $330
Updated: 2021/12/16

ChemScene

Product number: CS-W006326
Product name: (4-Amino-3-methoxyphenyl)methanol
Packaging: 5g
Price: $347
Updated: 2021/12/16

ChemScene

Product number: CS-W006326
Product name: (4-Amino-3-methoxyphenyl)methanol
Packaging: 250mg
Price: $50
Updated: 2021/12/16

Apolloscientific

Product number: OR926918
Product name: (4-Amino-3-methoxyphenyl)methanol
Purity: 95+%
Packaging: 250mg
Price: $57
Updated: 2021/12/16

ChemScene

Product number: CS-W006326
Product name: (4-Amino-3-methoxyphenyl)methanol
Packaging: 1g
Price: $114
Updated: 2021/12/16

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(4-AMINO-3-METHOXYPHENYL)METHANOL Chemical Properties,Usage,Production

Uses

(4-Amino-3-methoxyphenyl)methanol is a key intermediate in cyclotriveratrylene chemistry.

Synthesis

80866-88-2

148459-54-5

3-Methoxy-4-nitrobenzyl alcohol (5 g, 27 mmol) was used as starting material, which was dissolved in methanol (250 mL) and subsequently transferred to a reaction flask containing 10% Pd-C catalyst (5 mol%). The reaction mixture was stirred and reacted overnight under hydrogen atmosphere. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth plug and the filtrate was concentrated. The crude product was purified by silica gel column chromatography using EtOAc/hexane as eluent to give the final 4-amino-3-methoxybenzyl alcohol as a colorless oil (0.5 g, 15% yield).

References

[1] Bulletin de la Societe Chimique de France, 1993, vol. 130, # 1, p. 93 - 95
[2] Patent: WO2005/97752, 2005, A1. Location in patent: Page/Page column 124-125
[3] Tetrahedron, 2004, vol. 60, # 19, p. 4295 - 4302
[4] Patent: US5994368, 1999, A
[5] Patent: US6008229, 1999, A

(4-AMINO-3-METHOXYPHENYL)METHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(4-AMINO-3-METHOXYPHENYL)METHANOL Suppliers

China 47 India 2 Switzerland 1 United Kingdom 1 United States 5 Global 56

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View Lastest Price from (4-AMINO-3-METHOXYPHENYL)METHANOL manufacturers

Career Henan Chemical Co

Product: (4-AMINO-3-METHOXYPHENYL)METHANOL 148459-54-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-09

148459-54-5, (4-AMINO-3-METHOXYPHENYL)METHANOLRelated Search:

Methyl 4-amino-3-methoxybenzoate 4-Amino-3-methoxybenzoic acid 3-Methoxy-4-nitrobenzoic acid Benoxinate Hydrochloride 3-METHOXY-4-NITROBENZYL ALCOHOL Oxybuprocaine 4-Amino-3-(trifluoromethoxy)benzoic acid Methyl 3-methoxy-4-nitrobenzoate NITR 5/AM ETHYL 2-(4-AMINO-3-METHOXYPHENYL)-3,3,3-TRIFLUORO-2-HYDROXYPROPANOATE 3-BUTOXY-4-NITROBENZOIC ACID 1-[2-AMINO-5-(1-HYDROXY-1-(2-NITRO-4,5-METHYLENEDIOXYPHENYL))METHYL)PHENOXY]-2-(2'-AMINO-5'-METHYLPHENOXY)CYCLOPENTANE-N,N,N',N'-TETRAACETIC ACID, 4NA 5-(METHOXYCARBONYL)-2-NITROPHENYL 2-THIOPHENECARBOXYLATE nitr 5 NITR 5 TETRASODIUM SALT AURORA KA-6179 AURORA 1315 nitr 2

(4-AMINO-3-METHOXYPHENYL)METHANOL

[4-Amino-3-(methyloxy)phenyl]methanol

BenzeneMethanol,4-aMino-3-Methoxy-

4-Amino-3-methoxy-benzenemethanol

4-Amino-3-methoxybenzyl Alcohol

148459-54-5