(4-AMINO-3-METHOXYPHENYL)METHANOL
- Product Name
- (4-AMINO-3-METHOXYPHENYL)METHANOL
- CAS No.
- 148459-54-5
- Chemical Name
- (4-AMINO-3-METHOXYPHENYL)METHANOL
- Synonyms
- 4-Amino-3-methoxybenzyl Alcohol;(4-AMINO-3-METHOXYPHENYL)METHANOL;4-Amino-3-methoxy-benzenemethanol;BenzeneMethanol,4-aMino-3-Methoxy-;[4-Amino-3-(methyloxy)phenyl]methanol
- CBNumber
- CB9774616
- Molecular Formula
- C8H11NO2
- Formula Weight
- 153.18
- MOL File
- 148459-54-5.mol
(4-AMINO-3-METHOXYPHENYL)METHANOL Property
- Boiling point:
- 312℃
- Density
- 1.182
- Flash point:
- 142℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Appearance
- Light brown to yellow Liquid
- InChI
- InChI=1S/C8H11NO2/c1-11-8-4-6(5-10)2-3-7(8)9/h2-4,10H,5,9H2,1H3
- InChIKey
- RVYSKGNWKIIUIF-UHFFFAOYSA-N
- SMILES
- C1(CO)=CC=C(N)C(OC)=C1
Safety
- HS Code
- 2922500090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- A634810
- Product name
- (4-Amino-3-methoxyphenyl)methanol
- Packaging
- 1g
- Price
- $330
- Updated
- 2021/12/16
- Product number
- CS-W006326
- Product name
- (4-Amino-3-methoxyphenyl)methanol
- Packaging
- 5g
- Price
- $347
- Updated
- 2021/12/16
- Product number
- CS-W006326
- Product name
- (4-Amino-3-methoxyphenyl)methanol
- Packaging
- 250mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- OR926918
- Product name
- (4-Amino-3-methoxyphenyl)methanol
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $57
- Updated
- 2021/12/16
- Product number
- CS-W006326
- Product name
- (4-Amino-3-methoxyphenyl)methanol
- Packaging
- 1g
- Price
- $114
- Updated
- 2021/12/16
(4-AMINO-3-METHOXYPHENYL)METHANOL Chemical Properties,Usage,Production
Uses
(4-Amino-3-methoxyphenyl)methanol is a key intermediate in cyclotriveratrylene chemistry.
Synthesis
80866-88-2
148459-54-5
3-Methoxy-4-nitrobenzyl alcohol (5 g, 27 mmol) was used as starting material, which was dissolved in methanol (250 mL) and subsequently transferred to a reaction flask containing 10% Pd-C catalyst (5 mol%). The reaction mixture was stirred and reacted overnight under hydrogen atmosphere. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth plug and the filtrate was concentrated. The crude product was purified by silica gel column chromatography using EtOAc/hexane as eluent to give the final 4-amino-3-methoxybenzyl alcohol as a colorless oil (0.5 g, 15% yield).
References
[1] Bulletin de la Societe Chimique de France, 1993, vol. 130, # 1, p. 93 - 95
[2] Patent: WO2005/97752, 2005, A1. Location in patent: Page/Page column 124-125
[3] Tetrahedron, 2004, vol. 60, # 19, p. 4295 - 4302
[4] Patent: US5994368, 1999, A
[5] Patent: US6008229, 1999, A
(4-AMINO-3-METHOXYPHENYL)METHANOL Preparation Products And Raw materials
Raw materials
Preparation Products
(4-AMINO-3-METHOXYPHENYL)METHANOL Suppliers
- Tel
- --
- Fax
- --
- enquiries@fluorochem.co.uk
- Country
- United Kingdom
- ProdList
- 6401
- Advantage
- 74
View Lastest Price from (4-AMINO-3-METHOXYPHENYL)METHANOL manufacturers
- Product
- (4-AMINO-3-METHOXYPHENYL)METHANOL 148459-54-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-09