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DIETHYLALUMINUM CHLORIDE

Product Name
DIETHYLALUMINUM CHLORIDE
CAS No.
96-10-6
Chemical Name
DIETHYLALUMINUM CHLORIDE
Synonyms
DEAC;DIETHYLALUMINIUM CHLORIDE;Diethylaluminum;uminum chL;Diethylchoroaluminum;CHLORODIETHYLALUMINUM;chlorodiethyl-aluminu;Diethylchloroaluminum;Et2AlCl 1M in heptane;chloro(diethyl)alumane
CBNumber
CB9783672
Molecular Formula
C4H10AlCl
Formula Weight
120.56
MOL File
96-10-6.mol
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DIETHYLALUMINUM CHLORIDE Property

Melting point:
-85°C
Boiling point:
125°C 50mm
Density 
0.887 g/mL at 25 °C
vapor pressure 
3 mmHg ( 60 °C)
Flash point:
−9 °F
storage temp. 
0-6°C
solubility 
Miscible with hexane.
form 
Solution
Specific Gravity
0.711 (20/4℃）
color 
Colorless
Water Solubility 
reac H2O [CRC10]
Sensitive 
Air & Moisture Sensitive
Merck 
326
BRN 
4123259
CAS DataBase Reference
96-10-6(CAS DataBase Reference)
EPA Substance Registry System
Aluminum, chlorodiethyl- (96-10-6)
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Safety

Hazard Codes 
F,C,N
Risk Statements 
14-17-34-67-65-62-51/53-48/20-14/15-11-63-50/53
Safety Statements 
36/37/39-45-62-61-43-26-16
RIDADR 
UN 3394 4.2/PG 1
WGK Germany 
2
RTECS 
BD0558000
F 
10
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
I
HS Code 
29319090
Hazardous Substances Data
96-10-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H304May be fatal if swallowed and enters airways

H314Causes severe skin burns and eye damage

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
256714
Product name
Diethylaluminum chloride
Purity
97%
Packaging
100g
Price
$358
Updated
2024/03/01
Sigma-Aldrich
Product number
192732
Product name
Diethylaluminum chloride solution
Purity
25 wt. % in toluene
Packaging
100g
Price
$105.6
Updated
2024/03/01
Sigma-Aldrich
Product number
212806
Product name
Diethylaluminum chloride solution
Purity
1.0?M in hexanes
Packaging
4X25ML
Price
$86.3
Updated
2023/06/20
Sigma-Aldrich
Product number
212806
Product name
Diethylaluminum chloride solution
Purity
1.0?M in hexanes
Packaging
100ML
Price
$90.9
Updated
2023/06/20
Sigma-Aldrich
Product number
212806
Product name
Diethylaluminum chloride solution
Purity
1.0?M in hexanes
Packaging
800ML
Price
$332
Updated
2023/06/20
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DIETHYLALUMINUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

colorless solution

Chemical Properties

The aluminum alkyl halides are flammable, reactive, and may be spontaneously combustible in air. They are colorless to yellow liquids. Ethylaluminum dichloride:(563-43-9):

Production Methods

Ethylaluminum sesquichloride (26.5 kg) added to a nitrogen-purged reactor, was heated to 175 ℃. Then, while the mixture was stirred vigorously, 1.1 kg sodium was added over a 30 min period; the mixture was further heated at 155 – 190 ℃ for 60 min. The diethylaluminum chloride product distilled from the reactor at 100 – 161 ℃ (1.3 – 6.1 kPa). In this example, an excess of ethylaluminum sesquichloride was employed to facilitate draining the voluminous byproduct salt and aluminum solids from the reactor. In an alternate approach, a heavy hydrocarbon oil, added prior to reaction, may be employed to remove the solids in slurry form, permitting the use of a stoichiometric ratio of ethylaluminum sesquichloride and sodium reactants.

General Description

Colorless liquid. Dangerous fire and explosion hazard. Used as an intermediate in production of organometallics.

Air & Water Reactions

Pyrophoric in air [Hawley]. Reacts violently with water, Rose(1961).

Reactivity Profile

Organometallics, such as DIETHYLALUMINUM CHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.

Potential Exposure

These materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkyls

Shipping

UN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)

Purification Methods

Distil it from excess dry NaCl (to remove ethyl aluminium dichloride) in a 50-cm column containing a heated nichrome spiral. [Beilstein 4 IV 4403.]

Incompatibilities

The aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.

DIETHYLALUMINUM CHLORIDE Preparation Products And Raw materials

Raw materials

Activator reagent Triethylaluminum Sodium CHLOROETHANE Aluminum Aluminium magnesium alloy powder Ethyl aluminum chloride

Preparation Products

titanium trichloride/aluminum dialkyl chloride 2,6-Diethylaniline 1,2,5,6,9,10-Hexabromocyclododecane Polypropylene
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DIETHYLALUMINUM CHLORIDE Suppliers

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View Lastest Price from DIETHYLALUMINUM CHLORIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
DIETHYLALUMINUM CHLORIDE 96-10-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
DIETHYLALUMINUM CHLORIDE 96-10-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Zhuozhou Wenxi import and Export Co., Ltd
Product
DIETHYLALUMINUM CHLORIDE 96-10-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

96-10-6, DIETHYLALUMINUM CHLORIDERelated Search:

DIETHYLPHOSPHINIC CHLORIDE Acrylonitrile SALICYLALDEHYDE HYDRAZONE Dichloroaluminum Aluminum chloride Diethylzinc Trimethylaluminium DIMETHYLZINC Diisobutylaluminium hydride Aluminium hydride HEXANES Hexane ETHYLALUMINUM SESQUICHLORIDE DIMETHYLALUMINUM CHLORIDE DIETHYLALUMINUM CHLORIDE Dimethylaluminum hydride hydrochloric acid in ethanol DIISOBUTYLALUMINUM CHLORIDE

  • aluminiumdiethylchloride
  • Aluminum, chlorodiethyl-
  • Diethylchoroaluminum
  • DEAC
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  • DIETHYLALUMINIUM CHLORIDE
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  • Aluminiumdiethylmonochlorid
  • DiethylaluMinuM chloride, 2.0 M solution in hexanes, J&KSeal
  • DiethylaluMinuM chloride, 0.9 M solution in toluene, J&KSeal
  • DiethylaluMinuM chloride, 1.0 M solution in hexanes, J&KSeal
  • DiethylaluMinuM chloride, 0.9 M solution in Toluene, SpcSeal
  • DiethylaluMinuM chloride, 1.0 M solution in Hexanes, SpcSeal
  • DiethylaluMinuM chloride, 2.0 M solution in hexanes, SpcSeal
  • Aluminum,chlorodiethyl-
  • aluminumdiethylmonochloride
  • Chloro(diethyl)aluminium
  • chlorodiethyl-aluminu
  • dichlorotetraethyldi-aluminu
  • Diethylaluminum
  • Diethylaluminum monochloride
  • diethylaluminummonochloride
  • Diethylchloroaluminum
  • Diethylaluminum Chloride (ca. 15% in Hexane, ca. 0.87mol/L)
  • Chlorodiethylaluminum: (Diethylaluminum chloride)
  • Diethylaluminium chloride, 1.1M solution in toluene
  • Diethylaluminium chloride1.1M solution in tolueneAcroSeal§3
  • Diethylaluminium chloride1M solution in hexanesAcroSeal§3
  • Diethylaluminium chloride0.9M solution in tolueneAcroSeal§3
  • DIETHYLALMINIUMCHLORIDE
  • Diethylaluminum chloride, 96%, 25% w/w in heptane
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  • Diethylaluminum chloride solution 25t. % in toluene
  • Diethylaluminum chloride 97%
  • Diethylaluminium chloride, 0.9M solution in toluene, AcroSeal
  • Diethylaluminium chloride, 1.1M solution in toluene, AcroSeal
  • Diethylaluminium chloride, 1M solution in hexanes, AcroSeal
  • Diethylaluminum chloride, 97% (Material solid in non-returnable cylinder)
  • Diethylaluminum Chloride, 25% in Toluene
  • uminum chL
  • DIETHYLALUMINUM CHLORIDE ISO 9001：2015 REACH
  • Et2AlCl 1M in heptane
  • Diethylaluminum Chloride - 25% in Toluene (about 2M)
  • Diethylaluminum Chloride Solution (1M in hexanes)
  • chloro(diethyl)alumane