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CU-TMEDA CATALYST

Product Name
CU-TMEDA CATALYST
CAS No.
30698-64-7
Chemical Name
CU-TMEDA CATALYST
Synonyms
chlorocopper;Di-mu-hydroxo-bi;CU-TMEDA CATALYST;enediamine)copper(II)] ChL;Di-μ-hydroxo-bis[(N,N,N',N'-tetramethyL;Di-mu-hydroxo-bis-[TEMEDcopper(II)]chloride;Di-Mu-hydroxo-bis-[TEMED copper(II)]chlorid;Dihydroxobistetramethylethylenediaminecopper;Di-μ-hydroxo-bis[(N,N,N'.N'-tetramethylethylenediamine);chlorohydroxo(n,n,n',n'-tetrametylethylenediamine)copper(ii)
CBNumber
CB9784200
Molecular Formula
C12H34Cl2Cu2N4O2
Formula Weight
464.42
MOL File
30698-64-7.mol
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CU-TMEDA CATALYST Property

Melting point:
138-148 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Water Solubility 
Soluble in water
form 
Powder
color 
Dark purple
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Safety

Risk Statements 
36/37/38
Safety Statements 
24/25
WGK Germany 
3
F 
10-23
HS Code 
29212900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
593192
Product name
Cu-TMEDA catalyst
Packaging
5g
Price
$57.54
Updated
2024/03/01
TCI Chemical
Product number
D2542
Product name
Di-μ-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride
Purity
>97.0%(T)
Packaging
5g
Price
$47
Updated
2024/03/01
TCI Chemical
Product number
D2542
Product name
Di-μ-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride
Purity
>97.0%(T)
Packaging
25g
Price
$154
Updated
2024/03/01
TRC
Product number
D460385
Product name
Di-Mu-hydroxo-bis[(N,N,N'',N''-tetramethylethylenediamine)copper(Ii)]Chloride
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
D460385
Product name
Di-Mu-hydroxo-bis[(N,N,N'',N''-tetramethylethylenediamine)copper(Ii)]Chloride
Packaging
50mg
Price
$45
Updated
2021/12/16
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CU-TMEDA CATALYST Chemical Properties,Usage,Production

Chemical Properties

dark purple powder

Uses

Catalyst for:

  • Asymmetric conjugate addition reactions
  • 1,3-dipolar cycloaddition of pyrazolidinone-based dipoles to terminal alkynes (precatalyst)
  • Oxidative N-arylation of imidazoles
  • Oxidative coupling copolymerization
  • Tandem phosphorous-carbon bond formation-oxyfunctionalization reactions
  • Benzylation and allylation of amides

CU-TMEDA CATALYST Preparation Products And Raw materials

Raw materials

Preparation Products

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CU-TMEDA CATALYST Suppliers

Americas 1 Belgium 1 China 52 Europe 1 Germany 2 India 4 Japan 3 Switzerland 1 United Kingdom 2 United States 6 Global 73
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80

30698-64-7, CU-TMEDA CATALYSTRelated Search:

Magnesium chloride Holmium(III) chloride hexahydrate Ytterbium(III) chloride hexahydrate Acetylcholine chloride LUTETIUM CHLORIDE HEXAHYDRATE DYSPROSIUM(III) CHLORIDE HEXAHYDRATE POLYETHYLENE, CHLORINATED Cesium chloride POLYETHYLENE, CHLORINATED GALLIUM(III) CHLORIDE Bismuth trichloride Silver chloride Thulium chloride INDIUM(III) CHLORIDE TETRAHYDRATE N,N,N',N'-Tetramethylethylenediamine Copper CU-TMEDA CATALYST Copper oxychloride

  • COPPER(II) CHLORIDE HYDROXIDE (N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE) COMPLEX DIMER
  • CHLOROHYDROXO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II)
  • Di-μ-hydroxo-bis[(N,N,N'.N'-tetramethylethylenediamine)
  • Copper(2+), di-m-hydroxybis(N1,N1,N2,N2-tetramethyl-1,2-ethanediamine-kN1,kN2)di-, chloride (1:2), stereoisomer
  • DI-Micron-Hydroxo-Bis-[(N N N N-Tetramethyl-Ethylenedia E)Copper(II)]Chloride
  • chlorocopper
  • Di-μ-hydroxo-bis[(N,N,N',N'-tetramethyL
  • enediamine)copper(II)] ChL
  • CU-TMEDA CATALYST
  • DI-MU-HYDROXO-BIS[(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(2)] CHLORIDE
  • DI-MU-HYDROXO-BIS[(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II)] CHLORIDE
  • DI-MU-HYDROXO-BIS[(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II)]DICHLORIDE
  • Di-?hydroxo-bis[(N,N,N,N-tetramethylethylenediamine)copper(II)] chloride
  • Dihydroxobistetramethylethylenediaminecopper
  • Di-micron-hydroxo-bis-[(N,N,N,N-tetramethylethylenediamine)copper(II)]chloride
  • Di-Micron-hydroxo-bis-[N,N,N',N'-tetramethyl-ethylenediamine)copper(II)]chloride
  • Di-my-hydroxo-bis(N,N,N',N'-tetramethylethylenediamine)copper(II) chloride
  • Di-hydroxo-bis[(N,N,N,N-tetramethylethylenediamine)copper(II)]dichloride
  • chlorohydroxo(n,n,n',n'-tetrametylethylenediamine)copper(ii)
  • Cu-TMEDA catalyst, Copper(II) chloride hydroxide (N,N,Nμ,Nμ-tetrametylethylenediamine) Complex Dimer, Chlorohydroxo(N,N,Nμ,Nμ-tetrametylethylenediamine)copper(II)
  • Di-μ-hydroxo-bis-[(N,N,N',N'-tetramethylethylenediamine)copper(II)]chloride,98%
  • Di-mu-hydroxo-bi
  • Diu-hydroxo-bis[(N,N,N',N''-tetramethylethylenediamine)copper dichloride
  • Di-á-hydroxo-bis-[(N,N,N',N'-tetraMethylethylenediaMine)copper(II)]chloride, 98%
  • -hydroxo-bis[(<i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>'-tetramethylethylenediamine)copper(II)] Chloride
  • Di-mu-hydroxo-bis-[TEMEDcopper(II)]chloride
  • Di-mu-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)]Chloride&gt
  • Di-Micron-hydroxo-bis-[N,N,N',N'-tetramethyl-ethylenediamine...
  • Di-Mu-hydroxo-bis-[TEMED copper(II)]chlorid
  • Copper(2+), di-μ-hydroxybis(N1,N1,N2,N2-tetramethyl-1,2-ethanediamine-κN1,κN2)di-, chloride (1:2), stereoisomer
  • Bis(N1,N1,N2,N2-tetramethylethane-1,2-diamine)bis(hydroxycopper(II)) Dichloride
  • Di-μ-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride
  • chlorocopper N,N,N',N'-tetramethylethane-1,2-diamine dihydrate
  • 30698-64-7
  • C12H34Cl2Cu2N4O2
  • C12H34Cl2Cu2N9O8
  • 2C6H16N22ClCuHO
  • Catalysis and Inorganic Chemistry
  • Homogeneous Catalysts
  • Transition Metal Compounds
  • Catalysts for Organic Synthesis
  • Cu (Copper) Compounds
  • Classes of Metal Compounds
  • Metal Complexes
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Cu (Copper) Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Copper