3'-methoxypropiophenone

Product Name: 3'-methoxypropiophenone
CAS No.: 37951-49-8
Chemical Name: 3'-methoxypropiophenone
Synonyms: 3-methoxypropiophenone;3'-Methoxypropiophenone;Valerian root oil 8008-88-6;3'-Methoxypropiophenone, 99%;1-(3-Methoxyphenyl)-1-propanone;1-(3-methoxy-phenyl)propan-1-one;1-Propanone, 1-(3-methoxyphenyl)-
CBNumber: CB9910779
Molecular Formula: C10H12O2
Formula Weight: 164.2
MOL File: 37951-49-8.mol

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3'-methoxypropiophenone Property

Boiling point:: 259℃
Density: 1.0812
refractive index: 1.5230 (estimate)
storage temp.: Sealed in dry,Room Temperature
Appearance: Colorless to light yellow Liquid
InChI: InChI=1S/C10H12O2/c1-3-10(11)8-5-4-6-9(7-8)12-2/h4-7H,3H2,1-2H3
InChIKey: LPDJHUUWTGXTCU-UHFFFAOYSA-N
SMILES: C(C1=CC=CC(OC)=C1)(=O)CC

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Safety

HS Code: 2914500090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M331143
Product name: 3''-Methoxypropiophenone
Packaging: 50mg
Price: $60
Updated: 2021/12/16

Matrix Scientific

Product number: 075481
Product name: 3'-Methoxypropiophenone
Purity: 95+%
Packaging: 5g
Price: $163
Updated: 2021/12/16

Matrix Scientific

Product number: 075481
Product name: 3'-Methoxypropiophenone
Purity: 95+%
Packaging: 100mg
Price: $235
Updated: 2021/12/16

Matrix Scientific

Product number: 075481
Product name: 3'-Methoxypropiophenone
Purity: 95+%
Packaging: 25g
Price: $384
Updated: 2021/12/16

Rieke Metals

Product number: K0330211
Product name: 1-(3-Methoxy-phenyl)-propan-1-one
Packaging: 1g
Price: $527
Updated: 2021/12/16

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3'-methoxypropiophenone Chemical Properties,Usage,Production

Chemical Properties

3'-methoxypropiophenone is an organic compound belonging to the ketone class of compounds. It is a yellow to yellow brown liquid with a boiling point of 259 °C.

Uses

3'-methoxypropiophenone has a wide range of applications in the fields of medicine, chemistry, and industry.

Preparation

Preparation by reaction of ethylmagnesium bromide,
with m-methoxybenzonitrile (m.p. 60°)
with 3-methoxybenzaldehyde and oxidation of the resulting 1-(3-methoxyphenyl)-1-propanol with sodium dichromate in sulfuric acid (70%).

Synthesis

925-90-6

152121-82-9

37951-49-8

Under argon protection, 3,N-dimethoxy-N-methylbenzamide (5.86 g, 30.0 mmol) was dissolved in THF (150 mL) and cooled to 0°C. Slowly add ethylmagnesium bromide (0.960 mol/L THF solution, 100 mL, 96.0 mmol). After addition, bring to room temperature and stir for 3.5 hours. Upon completion of the reaction, the reaction was quenched with 1 mol/L hydrochloric acid and subsequently extracted with ethyl acetate. The organic layers were combined, washed sequentially with water and saturated saline, and dried over anhydrous sodium sulfate. Concentration under reduced pressure afforded m-methoxypropiophenone (4.93 g, 30.0 mmol, quantitative yield) as a yellow oil.1H-NMR (400 MHz, CDCl3): δ 1.23 (3H, t, J = 7.3 Hz), 3.00 (2H, q, J = 7.3 Hz), 3.86 (3H, s), 7.10 (1H, dd, J = 7.9 , 2.4 Hz), 7.37 (1H, t, J = 7.9 Hz), 7.50 (1H, t, J = 2.4 Hz), 7.54 (1H, d, J = 7.9 Hz).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2013, vol. 23, # 1, p. 375 - 381
[2] Patent: WO2007/62190, 2007, A2. Location in patent: Page/Page column 29; 30
[3] Patent: WO2007/62145, 2007, A2. Location in patent: Page/Page column 41
[4] Patent: WO2007/44796, 2007, A2. Location in patent: Page/Page column 35-36
[5] Angewandte Chemie - International Edition, 2016, vol. 55, # 52, p. 16115 - 16118

3'-methoxypropiophenone Preparation Products And Raw materials

Raw materials

Preparation Products

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3'-methoxypropiophenone Suppliers

China 164 Europe 2 Germany 3 India 14 United Kingdom 1 United States 10 Global 194

Changzhou Luowan Biological Technology Co., Ltd.

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Syntechem Co.,Ltd

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View Lastest Price from 3'-methoxypropiophenone manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 3'-methoxypropiophenone 37951-49-8
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-05

Henan Aochuang Chemical Co.,Ltd.

Product: 3'-methoxypropiophenone 37951-49-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-28

Shaanxi Dideu New Materials Co. Ltd

Product: 3'-methoxypropiophenone 37951-49-8
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-03-10

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3'-Methoxypropiophenone

3-methoxypropiophenone

3'-Methoxypropiophenone, 99%

37951-49-8