6-Bromonaphthalen-2-amine
- Product Name
- 6-Bromonaphthalen-2-amine
- CAS No.
- 7499-66-3
- Chemical Name
- 6-Bromonaphthalen-2-amine
- Synonyms
- F0701-0046;NSC 407685;2-Amino-6-bromophthalene;6-Bromonaphthalen-2-amine;6-BroMo-2-naphthalenaMine;2-Amino-6-bromonaphthalene;6-broMo-2-aMinonaphthalene;6-Bromonaphthalene-2-amine;2-Naphthalenamine, 6-bromo-;6-Bromonaphthalen-2-ylamine
- CBNumber
- CB9958050
- Molecular Formula
- C10H8BrN
- Formula Weight
- 222.08
- MOL File
- 7499-66-3.mol
6-Bromonaphthalen-2-amine Property
- Melting point:
- 128 °C
- Boiling point:
- 155-160 °C(Press: 1 Torr)
- Density
- 1.563±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- form
- solid
- pka
- 3.66±0.10(Predicted)
- color
- grey
- InChI
- InChI=1S/C10H8BrN/c11-9-3-1-8-6-10(12)4-2-7(8)5-9/h1-6H,12H2
- InChIKey
- UBLKHAWYJFEPDX-UHFFFAOYSA-N
- SMILES
- C1=C2C(C=C(Br)C=C2)=CC=C1N
Safety
- Hazard Note
- Irritant
- HS Code
- 2921450090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B685940
- Product name
- 6-Bromo-2-naphthylamine
- Packaging
- 1g
- Price
- $85
- Updated
- 2021/12/16
- Product number
- 047803
- Product name
- 2-Amino-6-bromonaphthalene
- Packaging
- 10g
- Price
- $103
- Updated
- 2021/12/16
- Product number
- CS-W001636
- Product name
- 6-Bromonaphthalen-2-amine
- Purity
- 96.48%
- Packaging
- 100g
- Price
- $415
- Updated
- 2021/12/16
- Product number
- 3630-9-X4
- Product name
- 2-Amino-6-bromonaphthalene
- Packaging
- 25g
- Price
- $552
- Updated
- 2021/12/16
- Product number
- HCH0002734
- Product name
- 2-AMINO-6-BROMONAPHTHALENE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $673.37
- Updated
- 2021/12/16
6-Bromonaphthalen-2-amine Chemical Properties,Usage,Production
Uses
6-Bromonaphthalen-2-amine is used in the new synthesis of alkylsulphanylnaphthalenes and the synthesis and mesomorphic properties of novel naphthylisothiocyanates.
Application
6-Bromonaphthalen-2-amine can be used to prepare light-emitting diode materials, amine compounds, deuterated aromatic compounds and deuterated compositions thereof.
Synthesis
6-Bromo-2-naphthoic acid (5.07g, 20.19mmol) and triethylamine (4.22mL, 3.07g, 30.3mmol) in dry DMF (155mL) were treated with the diphenylphosphoroyl azide (6.55mL, 8.34g, 30.3mmol) followed by stirring at room temperature for 3h. The solution was then treated with water (2OmL) and warming at 1000C for Ih. The solution was cooled in the flask fitted with a short-path distillation head, and the DMF was removed by distillation under a high vacuum. The solid residue was dissolved in EtOAc and washed with a saturated sodium bicarbonate solution. Filtered through celite, the filtrate was washed with water (3x) and brine. Dried over, filtered, and concentrated under vacuum to give 6-Bromonaphthalen-2-amine as a beige solid (4.48g, 100 percent).
References
[1] Patent: WO2009/39127, 2009, A1. Location in patent: Page/Page column 175
[2] Patent: WO2009/39134, 2009, A1. Location in patent: Page/Page column 104
[3] Patent: WO2010/111437, 2010, A1. Location in patent: Page/Page column 74
[4] Bioorganic and Medicinal Chemistry Letters, 2016, vol. 26, # 15, p. 3793 - 3799
[5] Bioorganic and Medicinal Chemistry Letters, 2002, vol. 12, # 12, p. 1651 - 1655
6-Bromonaphthalen-2-amine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 6-Bromonaphthalen-2-amine manufacturers
- Product
- 6-Bromonaphthalen-2-amine 7499-66-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 20tons
- Release date
- 2025-08-21
- Product
- 6-bromonaphthalen-2-amine 7499-66-3
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 0.99
- Supply Ability
- 1TONS
- Release date
- 2025-06-06
- Product
- 6-bromonaphthalen-2-amine 7499-66-3
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 0.99
- Supply Ability
- 1000KG
- Release date
- 2025-04-22