(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Basic information
- Product Name:
- (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
- Synonyms:
-
- (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
- (S,S)-NORPHOS
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene,min.95%(S,S)-NORPHOS
- (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE (S,S)-NORPHOS, (C 1,CHCL3)
- (1S,4R)-5α,6β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene
- [[1R,4S,(+)]-Bicyclo[2.2.1]hept-5-ene-2α,3β-diyl]bis(diphenylphosphine)
- [[1R,4S,(+)]-Bicyclo[2.2.1]hepta-5-ene-2α,3β-diyl]bis(diphenylphosphine)
- CAS:
- 71042-54-1
- MF:
- C31H28P2
- MW:
- 462.5
- Product Categories:
-
- Chiral Phosphine
- NORPhos Series
- organophosphine ligand
- Mol File:
- 71042-54-1.mol
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Chemical Properties
- Melting point:
- 120 °C
- alpha
- +47° (c 1, CHCl3)
- Boiling point:
- 577.0±50.0 °C(Predicted)
- form
- crystal
- color
- white
- Sensitive
- air sensitive
- CAS DataBase Reference
- 71042-54-1
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Safety Information
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- TSCA
- No
- HS Code
- 29310099
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Usage And Synthesis
Reaction
- Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
- Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
- Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
Chemical Properties
White crystalline powder
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENESupplier
J & K SCIENTIFIC LTD.
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Energy Chemical
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Shanghai Longsheng chemical Co.,Ltd.
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- 021-58099652-8005 13585536065
- bin.wu@shlschem.com
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE(71042-54-1)Related Product Information
- (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE
- Diphenylphosphine
- (S)-(-)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
- 1,2-Bis(diphenylphosphino)ethane
- 1,5-Bis(diphenylphosphino)pentane
- 1,2-BIS(PHENYLPHOSPHINO)ETHANE
- diphenyl(2-phosphinoethyl)phosphine
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh
- 1,2-Bis-(diphenylphosphino)propane
- Norbornene
- (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
- (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE