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Methyl 1-methylpiperidine-3-carboxylate

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Methyl 1-methylpiperidine-3-carboxylate Basic information

Product Name:
Methyl 1-methylpiperidine-3-carboxylate
Synonyms:
  • 1-methyl-3-piperidinecarboxylicacimethylester
  • 1-methylnipecoticacidmethylester
  • 1-methyl-nipecoticacimethylester
  • dihydroarecoline
  • methyln-methylnipecotate
  • Methyl 1-methylpiperidine-3-carboxylate CAS no. 1690-72-8
  • n-methyl-3-carbomethoxypiperidine
  • 1-Methyl-3-Piperidinelarboxylate
CAS:
1690-72-8
MF:
C8H15NO2
MW:
157.21
EINECS:
210-314-1
Product Categories:
  • Heterocyclic Compounds
Mol File:
1690-72-8.mol
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Methyl 1-methylpiperidine-3-carboxylate Chemical Properties

Boiling point:
bp12 83-84°
Density 
1.013±0.06 g/cm3(Predicted)
refractive index 
nD25 1.4520
storage temp. 
2-8°C
pka
pKa (20°): 8.66
CAS DataBase Reference
1690-72-8(CAS DataBase Reference)
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Safety Information

HS Code 
2933399990
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Methyl 1-methylpiperidine-3-carboxylate Usage And Synthesis

Uses

Methyl 1-methylpiperidine-3-carboxylate belongs to the class of organic compounds known as piperidinecarboxylic acids. Piperidinecarboxylic acids are compounds containing a piperidine ring with a carboxylic acid group. Methyl 1-methylpiperidine-3-carboxylate is a strong basic compound (based on its pKa). It could be used to synthesize (1-methylpiperidin-3-yl)methanol. The specific steps are shown as follows: into a 500 mL round bottom flask containing a solution of methyl 1-methylpiperidine-3- carboxylate (12.0 g, 76 mmol) in tetrahydrofuran (500 mL) was added lithium aluminumhydride (4.3 g, 114 mmol) in portions at 0 °C. The reaction mixture was stirred at room temperature for 1 h. The reaction was quenched with methanol at 0 °C, and the precipitated solid was filtered through celite. The filtrate was concentrated and the crude was purified by flash chromatography eluting with methanol in dichloromethane (5-10percent) to afford (1-methylpiperidin-3-yl)methanol as a solid.

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