HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I) Basic information
- Product Name:
- HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
- Synonyms:
-
- CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
- HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
- Hydridocarbonyltris-(triphenylphosphino)-iridium
- Carbonylhydridotris(triphenylphosphine)iridium(I), Ir 18.6% min
- Carbonylhydridotris(triphenylphosphine)iridium(I) slowly decomposes in air
- iridium(I)-tris(triphenylphosphine) carbonyl hydride
- carbonylhydrotris(triphenylphosphine)-iridiu
- HydridocarbonyltristriphenylphosphineiridiumIlightyellow
- CAS:
- 17250-25-8
- MF:
- C55H45IrOP3
- MW:
- 1007.08
- EINECS:
- 241-282-7
- Product Categories:
-
- Ir
- metal carbonyl complexes
- Mol File:
- 17250-25-8.mol
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HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I) Chemical Properties
- Melting point:
- 170°C (dec.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Soluble in chloroform and toluene
- form
- Powder
- color
- light yellow
- Sensitive
- Moisture Sensitive
- CAS DataBase Reference
- 17250-25-8
- EPA Substance Registry System
- Iridium, carbonylhydrotris(triphenylphosphine)- (17250-25-8)
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- RIDADR
- UN2813
- TSCA
- Yes
- HS Code
- 2843.90.0000
- HazardClass
- 4.3
- PackingGroup
- III
MSDS
- Language:English Provider:ALFA
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HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I) Usage And Synthesis
Reaction
- Catalyst for ring-opening isomerization of unsymmetrically substituted methylenecyclopropanes into 1,3-dienes
- Catalyst for asymmetric transfer hydrogenation of aromatic ketones under base-free conditions
- Catalyst for C-F bond activation for the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
Chemical Properties
pale yellow powder
Uses
Hydridocarbonyltris(triphenylphosphine)iridium (I) (CAS# 17250-25-8) is a useful reagent used for Si-C bond cleavage, and as a catalyst in the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
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