Methyl 2-amino-3,5-dibromobenzoate Chemical Properties

Melting point:

89-91 °C(lit.)

Boiling point:

317.9±37.0 °C(Predicted)

Density 

1.907±0.06 g/cm3(Predicted)

storage temp. 

Keep in dark place,Inert atmosphere,Room temperature

pka

-0.30±0.10(Predicted)

Appearance

White to off-white Solid

BRN 

3257505

InChI

InChI=1S/C8H7Br2NO2/c1-13-8(12)5-2-4(9)3-6(10)7(5)11/h2-3H,11H2,1H3

InChIKey

NGXVMFCGYYHEGC-UHFFFAOYSA-N

SMILES

C(OC)(=O)C1=CC(Br)=CC(Br)=C1N

CAS DataBase Reference

606-00-8(CAS DataBase Reference)

EPA Substance Registry System

Benzoic acid, 2-amino-3,5-dibromo-, methyl ester (606-00-8)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36/37/39

WGK Germany 

3

TSCA 

Yes

HS Code 

29224999

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Methyl 2-amino-3,5-dibromobenzoate Usage And Synthesis

Chemical Properties

Solid crystals. 98% of industrial products have a melting point of 89-91 °C.

Uses

Methyl 2-amino-3,5-dibromobenzoate can be used in the synthesis of drug hexyl bromide.

Synthesis

Methyl 2-amino-3,5-dibromobenzoate can be obtained by bromination of methyl o-urethane.

References

[1] Patent: US5089653, 1992, A
[2] Tetrahedron Letters, 2002, vol. 43, # 6, p. 1117 - 1121
[3] Mitt. Lebensmittelunters. Hyg., 1939, vol. 30, p. 246,250
[4] Journal of the Association of Official Agricultural Chemists, 1942, vol. 25, p. 537,545
[5] Pharmaceutica Acta Helvetiae, 1937, vol. 12, p. 8

Methyl 2-amino-3,5-dibromobenzoate(606-00-8)Related Product Information

• Bensulfuron methyl
• 2-Aminobenzyl alcohol
• Methyl 4-aminobenzoate
• 4-Dimethylaminobenzoic acid
• Methylcyanocarbamate
• 2-Aminobenzaldehyde
• METHYL THIOPHENE-2-CARBOXYLATE
• Methyl formate
• Methyl acetate
• Methylparaben
• Methyl 2-bromobenzoate
• o-Anisidine
• Methyl acrylate
• Kresoxim-methyl
• Methyl anthranilate
• Methyl benzoate
• Methyl carbamate
• Thiophanate-methyl