PHENETHYLZINC BROMIDE Chemical Properties

Boiling point:

65 °C

Density 

0.965 g/mL at 25 °C

Flash point:

1 °F

storage temp. 

2-8°C

Water Solubility 

Reacts with water.

Sensitive 

Air Sensitive

Exposure limits

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

CAS DataBase Reference

308796-14-7

Safety Information

Hazard Codes 

F,Xn

Risk Statements 

14-19-22-36/38-40-36/37-11

Safety Statements 

16-26-33-36-36/37

RIDADR 

UN 2056 3/PG 2

WGK Germany 

1

HazardClass 

4.3

MSDS

• Language:English Provider:SigmaAldrich

PHENETHYLZINC BROMIDE Usage And Synthesis

Uses

Phenethylzinc bromide can be used as a reagent:

• In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
• To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
• To synthesize benzyl substituted thienopyrimidine derivatives.

PHENETHYLZINC BROMIDE(308796-14-7)Related Product Information

• 2-THIENYLZINC BROMIDE
• 3-METHYL-2-PYRIDYLZINC BROMIDE
• 2-TERT-BUTOXY-2-OXOETHYLZINC CHLORIDE
• 2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T&
• 4-METHYL-2-PYRIDYLZINC BROMIDE
• 2,4-DIFLUOROBENZYLZINC BROMIDE
• PHENETHYLZINC BROMIDE
• 3-CHLORO-5-FLUOROPHENETHYLZINC BROMIDE
• 4-FLUOROPHENETHYLZINC BROMIDE
• 3-CHLOROPHENETHYLZINC BROMIDE
• 2-METHYLPHENETHYLZINC BROMIDE
• 4-METHOXYPHENETHYLZINC BROMIDE
• 4-METHYLPHENETHYLZINC BROMIDE
• 3-METHYLPHENETHYLZINC BROMIDE
• 3-METHOXYPHENETHYLZINC BROMIDE
• 3-FLUOROPHENETHYLZINC BROMIDE
• 4-CHLOROPHENETHYLZINC BROMIDE
• 2-METHOXYPHENETHYLZINC BROMIDE