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Benzylchlorodimethylsilane

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Benzylchlorodimethylsilane Basic information

Product Name:
Benzylchlorodimethylsilane
Synonyms:
  • BENZYLCHLORODIMETHYLSILANE
  • BENZYLDIMETHYLCHLOROSILANE
  • Dimethylchlorobenzylsilane
  • Benzyldimethylchlorisilane
  • Benzene, [(chlorodiMethylsilyl)Methyl]-
  • benzylchlorodimethyl-silan
  • chlorodimethyl(phenylmethyl)-silan
  • Benzylchlorodimethylsilane>
CAS:
1833-31-4
MF:
C9H13ClSi
MW:
184.74
Product Categories:
  • Monochlorosilanes
  • Protection & Derivatization Reagents (for Synthesis)
  • Si (Classes of Silicon Compounds)
  • Si-Cl Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry
  • Protecting and Derivatizing Reagents
  • Protection and Derivatization
  • Silicon-Based
Mol File:
1833-31-4.mol
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Benzylchlorodimethylsilane Chemical Properties

Melting point:
<0°C
Boiling point:
101-103 °C/18 mmHg (lit.)
Density 
1.018 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.511(lit.)
Flash point:
194 °F
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
1.016
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
InChIKey
ABHNFDUSOVXXOA-UHFFFAOYSA-N
CAS DataBase Reference
1833-31-4(CAS DataBase Reference)
EPA Substance Registry System
Silane, chlorodimethyl(phenylmethyl)- (1833-31-4)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2987 8/PG 2
WGK Germany 
3
RTECS 
VV1810000
TSCA 
Yes
HS Code 
2931.90.6000
HazardClass 
8
PackingGroup 
II
Toxicity
LD50 ivn-mus: 56 mg/kg CSLNX* NX#04165

MSDS

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Benzylchlorodimethylsilane Usage And Synthesis

Uses

Benzylchlorodimethylsilane can be used to prepare:

  • A ferrocene based mesoporous catalyst, applicable in the oxidation of styrene.
  • Silylbissulfide named 3-(benzyldimethylsilyl)-1,3-bis(phenylthio)-1-propene.
  • Silyl enyne by reacting with 6-hept-1-yne and nBu-Li, for further use in the intramolecular cross-metathesis to yield silicon substituted diene.

Safety Profile

Poison by intravenous route.When heated to decomposition it emits toxic vapors ofCl- .

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