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N-BROMOPHTHALIMIDE

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N-BROMOPHTHALIMIDE Basic information

Product Name:
N-BROMOPHTHALIMIDE
Synonyms:
  • N-BROMOPHTHALIMIDE
  • N-Bromophthalimide, 98+%
  • N2-bromobenzene-1,2-dicarboxamide
  • N-Bromophthalimide,95%
  • 1H-Isoindole-1,3(2H)-dione,2-broMo-
  • 2-broMoisoindoline-1,3-dione
  • NSC 3525
  • N-Bromophthalimide 95%
CAS:
2439-85-2
MF:
C8H4BrNO2
MW:
226.03
EINECS:
219-467-9
Product Categories:
  • N-Substituted Maleimides, Succinimides & Phthalimides
  • N-Substituted Phthalimides
  • Synthetic Organic Chemistry
  • Carbonyl Compounds
  • Cyclic Imides
  • Organic Building Blocks
  • Miscellaneous
  • Bromination
  • Halogenation
Mol File:
2439-85-2.mol
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N-BROMOPHTHALIMIDE Chemical Properties

Melting point:
194-198 °C (lit.)
Boiling point:
332.3±25.0 °C(Predicted)
Density 
1.932±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
pka
-3.53±0.20(Predicted)
color 
White to Light yellow to Light orange
Sensitive 
Moisture & Light Sensitive
BRN 
131211
CAS DataBase Reference
2439-85-2(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
10-21
HS Code 
29251900

MSDS

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N-BROMOPHTHALIMIDE Usage And Synthesis

Chemical Properties

Pale yellow to yellow powder

Uses

Brominating agent.

Uses

N-Bromophthalimide has been used:

  • as reagent in allylic amination reactions of alkenes
  • brominating reagent in enantioselective synthesis of multisubstituted biaryl derivatives by chiral phosphoric acid catalyzed asymmetric bromination
  • as a titrant in titrimetric determination of isoniazid in pure form or in tablets

Uses

N-BROMOPHTHALIMIDE (cas# 2439-85-2) is a useful catalyst for reactions such as the Hofmann-?Loffler reactions of sulfonimides under visible Light and the synthesis of naphthols via bromide-mediated intermolecular annulation.

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