Basic information Reactions Safety Supplier Related

(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL

Basic information Reactions Safety Supplier Related

(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL Basic information

Product Name:
(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
Synonyms:
  • 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol
  • 6,6'-Dibromo-2,2'-dihydroxy-1,1'-binaphthalene
  • 6,6'-Dibromo-1,1'-bi-2-naphthol 97%
  • AURORA KA-7214
  • (+/-)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
  • 6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
  • 6,6'-Dibromo-1,1'-bi-2-naphthol (RAC)
  • racemic-6,6'-Dibromo-1,1'-bi-2-naphthol,min.98%
CAS:
13185-00-7
MF:
C20H12Br2O2
MW:
444.12
Product Categories:
  • BINOL Series
  • Achiral Oxygen
  • Organic Building Blocks
  • Oxygen Compounds
  • Polyols
Mol File:
13185-00-7.mol
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(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL Chemical Properties

Melting point:
195-199 °C(lit.)
Boiling point:
546.2±45.0 °C(Predicted)
Density 
1.761
refractive index 
1.4947 (estimate)
storage temp. 
2-8°C
form 
Powder
pka
7.78±0.50(Predicted)
color 
white
CAS DataBase Reference
13185-00-7(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29072900

MSDS

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(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL Usage And Synthesis

Reactions

1. Ligand (enantiopure version) used to prepare a chiral zirconium catalyst useful in asymmetric Strecker and Mannich-type reactions.
2. Ligand (enantiopure version) used for titanium-catalyzed enantioselective Friedel-Crafts reactions.

Chemical Properties

white powder

General Description

6,6′-Dibromo-1,1′-bi-2-naphthol is a 1,1′-bi-2-naphthol derivative. Vibrational circular dichroism (VCD), electronic circular dichroism (ECD) and optical rotatory dispersion (ORD) spectra for the enantiomers of 6,6′-dibromo-1,1′-bi-2-naphthol have been evaluated.

(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOLSupplier

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