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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometalate >  (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE Basic information

Product Name:
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
Synonyms:
  • (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINIUM(III) CHLORIDE
  • (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
  • Cyclohexanediaminobisdibutylsalicyliden
  • (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]aluminum(III)chloride
  • (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%
  • (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
  • (1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluMinuM(III) chloride,98% (R,R)-Salen-Al
  • (R,R)Salen AI
CAS:
250611-13-3
MF:
C36H52AlClN2O2
MW:
607.24
Product Categories:
  • Jacobsen Metal
Mol File:
250611-13-3.mol
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE Chemical Properties

Melting point:
250-255 °C(lit.)
form 
Powder
color 
yellow
CAS DataBase Reference
250611-13-3
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
26-36
WGK Germany 
3
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE Usage And Synthesis

Reaction

  1. Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
  2. Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
  3. Catalyst used for the asymmetric hydrocyanation of nitroolefins.
  4. Catalyst used in the reaction of epoxides with heterocumulenes.

Uses

Catalyst for:

  • Asymmetric iodolactonizations
  • Cyanosilylation reactions
  • Phospho-aldol catalysis

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDESupplier

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