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BETA-D-GALACTOPYRANOSYL AZIDE

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BETA-D-GALACTOPYRANOSYL AZIDE Basic information

Product Name:
BETA-D-GALACTOPYRANOSYL AZIDE
Synonyms:
  • 1-AZIDO-1-DEOXY-BETA-D-GALACTOPYRANOSID&
  • 1-Azido-1-deoxy-β-D-galactopyranoside ,97%
  • b-D-Galactopyranosyl azide
  • 1-Azido-beta-galactose
  • 1-azido-1-deoxy-β-d-galactopyranoside
  • 1-Azido-1-deoxy-b-D-galactopyranoside
  • 2-azido-6-(hydroxymethyl)oxane-3
  • 5-triol 35899-89-9 AC1NN2OA 1-Azido-1-deoxy-b-D-galactopyranoside A823031
CAS:
35899-89-9
MF:
C6H11N3O5
MW:
205.16864
EINECS:
1533716-785-6
Product Categories:
  • Carbohydrate Synthesis
  • Click Chemistry
  • MonosaccharidesChemical Ligation
  • Organic Azides
  • Specialty Synthesis
Mol File:
35899-89-9.mol
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BETA-D-GALACTOPYRANOSYL AZIDE Chemical Properties

Melting point:
150 °C (dec.)(lit.)
storage temp. 
-20°C
form 
solid
optical activity
[α]20/D +23°, c = 1% in DMSO
InChI
1S/C6H11N3O5/c7-9-8-6-5(13)4(12)3(11)2(1-10)14-6/h2-6,10-13H,1H2/t2-,3+,4+,5-,6-/m1/s1
InChIKey
KSRDTSABQYNYMP-FPRJBGLDSA-N
SMILES
OC[C@H]1O[C@@H](N=[N+]=[N-])[C@H](O)[C@@H](O)[C@H]1O
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Safety Information

Safety Statements 
24/25
WGK Germany 
3
HS Code 
2938909090
Storage Class
11 - Combustible Solids
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BETA-D-GALACTOPYRANOSYL AZIDE Usage And Synthesis

Uses

b-D-Galactopyranosyl Azide is used in method for synthesizing sugar-containing dendrimer containing similar sugar unit.

reaction suitability

reaction type: click chemistry

Synthesis

Accurately weighed azide fully acetylated galactose (0.7466g, 2mmol) in a roundness flask containing 100mL of methanol, added CH3ONa (432.1mg, 8mmol), nitrogen protection, stirring at room temperature for 2h, TLC detection of the reaction was complete, the system pH was adjusted to 7 with an ion-exchange resin, filtration, concentration under reduced pressure, to obtain the yellow liquid compound 1- azido-1-deoxy-??-D-galactopyranoside, the reaction was completed. The yellow liquid compound 1-azido-1-deoxy-??-D-galactoside was obtained.

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