(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER
(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Basic information
- Product Name:
- (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER
- Synonyms:
-
- 4S,5S-diethyl 2,2-diMethyl-1,3-dioxolane-4,5-dicarboxylate
- Dimethyl (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylate (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic Acid Dimethyl Ester (+)-2,3-O-Isopropylidene-D-tartaric Acid Dimethyl Ester
- 2,2-Dimethyl-(4S-trans)-1,3-Dioxolane-4,5-dicarboxylic acid dimethyl ester
- Dimethyl (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic acid dimethyl ester
- (+)-Dimethyl 2,3-O-isopropylidene-D-tartrate,97%
- (+)-DiMethyl 2,3-O-isopropylidene-D-tartarate , GC 97%
- (+)-Dimethyl 2,3-O-isopropylidene-D-tartrate 98%
- (4S,5S)- 2,2-dimethyl-1,3-Dioxolane-4,5-dicarboxylic acid 4,5-dimethyl ester
- CAS:
- 37031-30-4
- MF:
- C9H14O6
- MW:
- 218.2
- Product Categories:
-
- chiral
- Amino Acids 13C, 2H, 15N
- Chiral Building Blocks
- Dioxanes & Dioxolanes
- Dioxolanes
- Esters (Chiral)
- Synthetic Organic Chemistry
- Amino Acids & Derivatives
- Mol File:
- 37031-30-4.mol
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(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Chemical Properties
- Boiling point:
- 80-82 °C0.1 mm Hg(lit.)
- alpha
- [α](c=1, CHCl3) +41.0~+45.0°
- Density
- 1.19 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.439(lit.)
- Flash point:
- 275 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform, Methanol
- form
- Liquid
- color
- Clear colorless to slightly yellow
- optical activity
- [α]20/D +54°, neat
- BRN
- 3548490
- InChIKey
- MCNKHXZIPATURB-YUMQZZPRSA-N
- CAS DataBase Reference
- 37031-30-4(CAS DataBase Reference)
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
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(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Usage And Synthesis
Chemical Properties
Colorless to light yellow liqui
Uses
(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate can be used as a starting material for the synthesis of:
- Deuterated 1-deoxy-D-xylose.
- C-terminal peptide -oxo-aldehydes using Fmoc solid-phase peptide synthesis methodology (SPPS).
- Bis-Weinreb amide, a key intermediate for the preparation of myo-inositol analog via ring-closing metathesis.
General Description
(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate is a chiral reagent used in organic synthesis. It is prepared by the reaction-rectification process from D -tartrate, and 2,2-dimethoxypropane.{138]
(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTERSupplier
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(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER(37031-30-4)Related Product Information
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