DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Basic information
- Product Name:
- DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
- Synonyms:
-
- DIETHYL PHENACYLPHOSPHONATE
- DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
- DIETHYL(2-OXO-2-PHENYL)PHOSPHONATE
- AIDS139382
- Diethyl (2-oxo-2-phenylethyl)phosphonate, 98+ %
- diethyl (2-oxo-2-phenethyl)phosphonate
- 2-Phenyl-2-oxoethylphosphonic acid diethyl ester
- α-(Diethoxyphosphinyl)acetophenone
- CAS:
- 3453-00-7
- MF:
- C12H17O4P
- MW:
- 256.23
- Product Categories:
-
- C-C Bond Formation
- Horner-Wadsworth-Emmons Reagents
- Olefination
- Mol File:
- 3453-00-7.mol
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DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Chemical Properties
- Boiling point:
- 192-193 °C/11 mmHg (lit.)
- Density
- 1.179 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.513(lit.)
- Flash point:
- >230 °F
- form
- clear liquid
- color
- White to Yellow to Green
- CAS DataBase Reference
- 3453-00-7
MSDS
- Language:English Provider:SigmaAldrich
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DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Usage And Synthesis
Uses
Reactant involved in:
- Asymmetric Michael addition of β-oxo phosphonates to nitro olefins
- Gem-chlorofluorination of keto phosphonates with subsequent functionalization of the products
- Cyclocondensation reactions to produce arylphosphonates
- Diazo transfer reactions for synthesis of diazo-phosphonyl compounds
- Horner-Wadsworth-Emmons reactions
- Inverse-electron-demand Diels-Alder reactions
Synthesis Reference(s)
Synthetic Communications, 26, p. 2561, 1996 DOI: 10.1080/00397919608004568
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