Basic information Safety Supplier Related

DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE

Basic information Safety Supplier Related

DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Basic information

Product Name:
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
Synonyms:
  • DIETHYL PHENACYLPHOSPHONATE
  • DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
  • DIETHYL(2-OXO-2-PHENYL)PHOSPHONATE
  • AIDS139382
  • Diethyl (2-oxo-2-phenylethyl)phosphonate, 98+ %
  • diethyl (2-oxo-2-phenethyl)phosphonate
  • 2-Phenyl-2-oxoethylphosphonic acid diethyl ester
  • α-(Diethoxyphosphinyl)acetophenone
CAS:
3453-00-7
MF:
C12H17O4P
MW:
256.23
Product Categories:
  • C-C Bond Formation
  • Horner-Wadsworth-Emmons Reagents
  • Olefination
Mol File:
3453-00-7.mol
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DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Chemical Properties

Boiling point:
192-193 °C/11 mmHg (lit.)
Density 
1.179 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.513(lit.)
Flash point:
>230 °F
form 
clear liquid
color 
White to Yellow to Green
CAS DataBase Reference
3453-00-7
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Safety Information

WGK Germany 
3
HS Code 
2931499090

MSDS

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DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Usage And Synthesis

Uses

Reactant involved in:

  • Asymmetric Michael addition of β-oxo phosphonates to nitro olefins
  • Gem-chlorofluorination of keto phosphonates with subsequent functionalization of the products
  • Cyclocondensation reactions to produce arylphosphonates
  • Diazo transfer reactions for synthesis of diazo-phosphonyl compounds
  • Horner-Wadsworth-Emmons reactions
  • Inverse-electron-demand Diels-Alder reactions

Synthesis Reference(s)

Synthetic Communications, 26, p. 2561, 1996 DOI: 10.1080/00397919608004568

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