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Dimethyl acetylmethylphosphonate

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Dimethyl acetylmethylphosphonate Basic information

Product Name:
Dimethyl acetylmethylphosphonate
Synonyms:
  • PHOSPHONIC ACID, (2-OXOPROPYL)-, DIMETHYL ESTER
  • LABOTEST-BB LT00847718
  • DIMETHYL (2-OXOPROPYL)PHOSPHONATE
  • DIMETHYL ACETONYLPHOSPHONATE
  • DIMETHYL ACETYLMETHYLPHOSPHONATE
  • Acetylmethylphosphonic acid dimethyl ester~Dimethyl acetonylphosphonate~Dimethyl (2-oxopropyl)phosphonate
  • Dimethyl(2-oxopropyl)phosph
  • Dimethylacetylmethylphosphonate,[Acetylmethylphosphonicaciddimethylester
CAS:
4202-14-6
MF:
C5H11O4P
MW:
166.11
EINECS:
224-110-5
Product Categories:
  • Horner-Emmons Reaction
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
Mol File:
4202-14-6.mol
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Dimethyl acetylmethylphosphonate Chemical Properties

Boiling point:
76-79 °C3 mm Hg(lit.)
Density 
1.202 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.439(lit.)
Flash point:
200 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Difficult to mix.
form 
Liquid
color 
Clear colorless to light brown
BRN 
1766218
InChIKey
UOWIYNWMROWVDG-UHFFFAOYSA-N
CAS DataBase Reference
4202-14-6(CAS DataBase Reference)
NIST Chemistry Reference
Dimethyl (2-oxopropyl)phosphonate(4202-14-6)
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Safety Information

Hazard Codes 
Xi
Safety Statements 
23-24/25
WGK Germany 
3
10
Hazard Note 
Irritant
HS Code 
29310095

MSDS

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Dimethyl acetylmethylphosphonate Usage And Synthesis

Chemical Properties

CLEAR COLOURLESS TO LIGHT BROWN LIQUID

Uses

Dimethyl acetylmethylphosphonate is a Reagent used together with tosyl azide in a one-pot alkynylation of aldehydes.

Synthesis Reference(s)

Tetrahedron Letters, 17, p. 2829, 1976 DOI: 10.1016/S0040-4039(01)85513-1

Dimethyl acetylmethylphosphonate Preparation Products And Raw materials

Raw materials

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