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ChemicalBook >  Product Catalog >  Organic Chemistry >  Heterocyclic Compounds >  (R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)

(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)

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(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Basic information

Product Name:
(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)
Synonyms:
  • (R)-(+)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE)
  • (R,R)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE
  • (R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)
  • (R,R)-2,2'-ISOPROPYLIDENEBIS(4-PHENYL-2-OXAZOLINE)
  • (R,R)-2,2μ-Isopropylidenebis(4-phenyl-2-oxazoline), (R,R)-2,2μ-Bis(4-phenyl-2-oxazolin-2-yl)propane
  • (+)-2,2'-isopropylidenebis[(4r)-4-phenyl-2-oxazoline]
  • (+)-2,2'-isopropylidenebis[(4r)-4-phenyl-2-oxazo
  • (R,R)-2,2'-(Dimethylmethylene)Bis(4-Phenyl-2-Oxazoline),96%
CAS:
150529-93-4
MF:
C21H22N2O2
MW:
334.41
Product Categories:
  • Chiral Nitrogen
  • BOX series
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
Mol File:
150529-93-4.mol
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(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Chemical Properties

Melting point:
56-58 °C(lit.)
Boiling point:
468.9±45.0 °C(Predicted)
Density 
1.18±0.1 g/cm3(Predicted)
refractive index 
160 ° (C=1, EtOH)
storage temp. 
-20°C
pka
4.85±0.70(Predicted)
form 
clear liquid
color 
Light yellow to Amber to Dark green
optical activity
[α]20/D +160°, c = 1 in ethanol
BRN 
4266906
CAS DataBase Reference
150529-93-4
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Safety Information

Hazard Codes 
T
Risk Statements 
23/24/25
Safety Statements 
26-36-45
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
HS Code 
29349990

MSDS

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(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE) Usage And Synthesis

Chemical Properties

Low melting solid or liquid

Uses

(+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline] in the presence of copper iodide, can catalyze the asymmetric cyclopropanation reaction of phenyliodonium ylides with alkenes to form cyclopropane α-amino acid esters.

(R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)Supplier

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