(4S 4'S)-(-)-2 2'-(3-PENTYLIDENE)BIS(4-& Chemical Properties

Boiling point:

120 °C/0.001 mmHg (lit.)

Density 

1.002 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.4710(lit.)

Flash point:

180 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

pka

5.51±0.70(Predicted)

Appearance

Colorless to light yellow Liquid

optical activity

-112.905°(C=1g/100ml CHCL3)

InChI

1S/C17H30N2O2/c1-7-17(8-2,15-18-13(9-20-15)11(3)4)16-19-14(10-21-16)12(5)6/h11-14H,7-10H2,1-6H3/t13-,14-/m1/s1

InChIKey

PIJFQTUSLZLNOP-ZIAGYGMSSA-N

SMILES

CCC(CC)(C1=N[C@H](CO1)C(C)C)C2=N[C@H](CO2)C(C)C

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

RIDADR 

NA 1993 / PGIII

WGK Germany 

3

HS Code 

29349990

Storage Class

10 - Combustible liquids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

(4S 4'S)-(-)-2 2'-(3-PENTYLIDENE)BIS(4-& Usage And Synthesis

Uses

(4S,4′S)-(?)-2,2′-(3-Pentylidene)bis(4-isopropyloxazoline) is a bisoxazoline that can be used as a ligand:

• To prepare [¹¹C]carboxylic acids, [¹¹C]esters and [¹¹C]amides using boronic acid esters and ¹¹CO₂.
• In one of the key synthetic steps for the total synthesis of tatanan A and 3-epi-tatanan A.
• To prepare copper(I) complex and used in a mass spectrometric method to study its chiral selectivity with different substrates.

(4S 4'S)-(-)-2 2'-(3-PENTYLIDENE)BIS(4-&(160191-65-1)Related Product Information

• (4S,4'S)- 2,2'-(1-ethylpropylidene)bis[4,5-dihydro-4-phenyl-Oxazole
• (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine
• (1S,2S)-(+)-N,N-Dimethylcyclohexane-1,2-diamine
• (4S,4'S)-2,2'-(Cyclopentane-1,1-diyl)-bis(4-isopropyl-4,5-dihydrooxazole)
• (R,R)-2,2'-(DIMETHYLMETHYLENE)BIS(4-PHENYL-2-OXAZOLINE)
• (+)-2 2'-ISOPROPYLIDENEBIS((4R)-4-BENZYL
• (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE
• 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
• (4R,4'R)-2,2'-(Cyclopentane-1,1-diyl)-bis(4-phenyl-4,5-dihydrooxazole)