Basic information Safety Supplier Related

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

Basic information Safety Supplier Related

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Basic information

Product Name:
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
Synonyms:
  • 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
  • 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D) OXAZOLIN-2-YL)PYRIDINE
  • (3aR,8aS)-in-pybox, (3aR,3μaR,8aS,8μaS)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
  • 2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
  • 8H-Indeno[1,2-d]oxazole,2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aR,3'aR,8aS,8'aS)-
  • (3aR,3'aR,8aS,8'aS)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
  • 2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine >=94%
  • 2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, >=98%
CAS:
357209-32-6
MF:
C25H19N3O2
MW:
393.44
Product Categories:
  • BOX series
  • Chiral Nitrogen
Mol File:
357209-32-6.mol
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2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Chemical Properties

Melting point:
284 °C (dec.)
Boiling point:
633.0±55.0 °C(Predicted)
Density 
1.50±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
4.35±0.20(Predicted)
optical activity
[α]20/D +386°, c = 1 in methylene chloride(lit.)
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29349990
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2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Usage And Synthesis

Chemical Properties

White powder

Uses

Catalytic ligand used for:

  • [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
  • Enantioselective Mukaiyama-aldol reactions
  • Enantioselective carbonyl-ene reactions
  • Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
  • Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
  • Enantioselective Diels-Alder reaction
  • Ni-catalyzed cross-coupling reactions

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&Supplier

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