ChemicalBook > Product Catalog > Organic Chemistry > Heterocyclic Compounds > (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Basic information
- Product Name:
- (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
- Synonyms:
-
- 2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine
- 2,6-Bis((S)
- -4-isopropyl-4,5-dihydrooxazol-2-yl)
- 2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e.
- (-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE
- 2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE
- 2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine ,99%
- (S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
- CAS:
- 118949-61-4
- MF:
- C17H23N3O2
- MW:
- 301.38
- Product Categories:
-
- organic amine
- BOX series
- Asymmetric Synthesis
- Synthetic Organic Chemistry
- Chiral Nitrogen
- Mol File:
- 118949-61-4.mol
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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Chemical Properties
- Melting point:
- 155-157 °C(lit.)
- alpha
- -120° (c 1.0, CH2Cl2)
- Boiling point:
- 457.1±30.0 °C(Predicted)
- Density
- 1.23±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,2-8°C
- pka
- 3.78±0.70(Predicted)
- form
- crystal
- color
- white
- optical activity
- [α]25/D 118°, c = 0.7 in methylene chloride
- BRN
- 5824976
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MSDS
- Language:English Provider:SigmaAldrich
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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Usage And Synthesis
Reaction
- Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
- Ligand for cross-coupling reactions of iodoalkanes with alkyl zinc halides.
- Ligand for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes.
- Ligand for asymmetric allylation of aldehydes with b-carbonyl allylstannanes.
- Ligand used in the enantioselective Negishi reaction of racemic secondary benzylic halides.
- Ligand for osmium catalyzed enantioselective transfer hydrogenation.
Chemical Properties
White powder or crystal or chunks
Uses
Used as a ligand to prepare novel ruthenium-pyridine-carboxylate complexes as new catalytic systems for alkene epoxidation.
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINESupplier
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J & K SCIENTIFIC LTD.
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(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE(118949-61-4)Related Product Information
- 2,6-Bis[(4S)-4-tert-butyloxazolin-2-yl]pyridine
- (R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
- 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine
- 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine
- 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
- (S)-5-CF3-pyrox-tBu
- 2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine
- 2,6-BIS[(4R)-4-TERT-BUTYL-2-OXAZOLIN-2YL]PYRIDINE
- 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine
- (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
- (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE
- (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE
- 2,6-BIS(2-BENZIMIDAZOLYL)PYRIDINE
- (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
- (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
- 2,6-Pyridinedimethanol
- METHYL PICOLINIMIDATE
- PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER