(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Basic information
- Product Name:
- (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
- Synonyms:
-
- (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX
- 2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
- (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
- (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97%
- aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine
- (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e.
- (-)-2,6-BIS[2-{3AS-(2(3'AR*,8'AS*),3AΑ,8AΑ)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE}]PYRIDINE
- 2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine
- CAS:
- 185346-09-2
- MF:
- C25H19N3O2
- MW:
- 393.44
- Product Categories:
-
- BOX series
- Chiral Nitrogen
- organic amine
- Mol File:
- 185346-09-2.mol
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(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Chemical Properties
- Melting point:
- 265°C (dec.)
- alpha
- -364.0° (c 1.04, CH2Cl2)
- Boiling point:
- 633.0±55.0 °C(Predicted)
- Density
- 1.50±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Powder
- pka
- 4.35±0.20(Predicted)
- color
- white to off-white
- optical activity
- [α]20/D -375°, c = 1 in dichloromethane (typical)
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Safety Information
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-36
- WGK Germany
- 3
- HS Code
- 29333990
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(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Usage And Synthesis
Reaction
- Ligand for Iridium-catalyzed enantio- and diastereoselective reductive aldol reactions
- Ligand for Scandium-catalyzed asymmetric Nazarov reactions
- Ligand for Scandium-catalyzed enantioselective pyrrole alkylations of α,β-unsaturated 2-acyl imidazoles
- Ligand for Scandium-catalyzed enantioselective Friedel-Crafts Alkylations
- Ligand for Nickel-catalyzed asymmetric cross-couplings of racemic propargyl groups with arylzinc reagents
- Ligand for Scandium-catalyzed enantioselective intramolecular carbonyl-ene reaction, the synthesis of (+)-triptophenolide
- Ligand for Scandium-catalyzed asymmetric synthesis of substituted 3-hydroxy-2-oxindoles
- Ligand for Indium-catalyzed enantio- and regioselective addition of pyrroles to isatins
- Ligand for Scandium-catalyzed asymmetric [3+2] annulation of allylsilanes with isatins in the synthesis of spirooxindoles
- Ligand for Scandium-catalyzed enantioselective allylation of isatins using allylsilanes
- Ligand for Scandium-catalyzed enantioselective carboannulation with allylsilanes
Chemical Properties
White powder
Uses
Reactant involved in synthesis of:
- Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
- Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
- Chiral N,N,N-tridentate pybos and pyboxazine ligands
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINESupplier
LaaJoo Gold
- Tel
- 021-60702684 18516024827
- huang.jiayi@sinocompound.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Nanjing Habo Medical Technology Co., Ltd.
- Tel
- 025-85760892 13376090521
- sales@habotech.com
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(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE(185346-09-2)Related Product Information
- 2,6-bis[(4R,5R)-4,5-dihydro-1-[(4-methylphenyl)sulfonyl]-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine
- 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine
- 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine
- 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
- (S)-5-CF3-pyrox-tBu
- 2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine
- (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
- (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE
- (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE
- 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine
- (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
- (1S,2R)-(-)-cis-1-Amino-2-indanol
- METHYL PICOLINIMIDATE
- PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER