2-Phenoxyethyl Acrylate Chemical Properties

Melting point:

-74 °C

Boiling point:

84 °C0.2 mm Hg(lit.)

Density 

1.104 g/mL at 25 °C(lit.)

vapor pressure 

0.25Pa at 25℃

refractive index 

n20/D 1.518(lit.)

Flash point:

>230 °F

storage temp. 

2-8°C

solubility 

Practically insoluble in water

form 

clear liquid

color 

Colorless to Almost colorless

Water Solubility 

525mg/L at 25℃

BRN 

2102773

Cosmetics Ingredients Functions

NAIL CONDITIONING

InChI

1S/C11H12O3/c1-2-11(12)14-9-8-13-10-6-4-3-5-7-10/h2-7H,1,8-9H2

InChIKey

RZVINYQDSSQUKO-UHFFFAOYSA-N

SMILES

C=CC(=O)OCCOc1ccccc1

LogP

2.58 at 25℃

CAS DataBase Reference

48145-04-6(CAS DataBase Reference)

EPA Substance Registry System

2-Phenoxyethyl acrylate (48145-04-6)

Safety Information

Hazard Codes 

Xi,N

Risk Statements 

36/37/38-51/53

Safety Statements 

26-28-61

RIDADR 

UN 3082 9 / PGIII

WGK Germany 

2

RTECS 

KM0700000

TSCA 

TSCA listed

HazardClass 

9

PackingGroup 

III

HS Code 

29161290

Storage Class

10 - Combustible liquids

Hazard Classifications

Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

2-Phenoxyethyl Acrylate Usage And Synthesis

Description

2-Phenoxyethyl acrylate is a nonflammable, low-volatility liquid with moderate solubility in water. 2-Phenoxyethyl acrylate is a monofunctional acrylic monomer that free radicals can polymerize. In particular, this compound is designed for ultraviolet and electron beam curing applications and used in U.V &E.B cured coatings, inks, and adhesives.

Uses

2-Phenoxyethyl Acrylate is used as a monomer in multifunctional and shape memory polymers.

Uses

Ethylene glycol phenyl ether acrylate (PA) monomer may be used to fabricate polymerization induced grating pattern on photopolymer films.

General Description

Ethylene glycol phenyl ether acrylate (PA) is a monofunctional acrylate.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by skin contact. Mdly toxic by ingestion. A skin irritant. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes

Synthesis

1) Measured phenol, ring-opening polymerization catalyst into the stainless steel high-pressure reactor, vacuum, heating to the appropriate reaction temperature, dropwise addition of ethylene oxide, temperature control reaction to the completion of the dropwise addition of ethylene oxide, and then held until the end of the reaction, cooling out of the material, to get the 2-phenoxyethanol intermediate.

2) The 2-phenoxyethanol intermediate was added to the homemade vacuum distillation device for vacuum distillation, and 2-phenoxyethanol was obtained by component separation.

3) The measured 2-phenoxyethanol, acrylic acid, p-toluenesulfonic acid, copper chloride dihydrate, p-hydroxyanisole, and cyclohexane were added to a four-necked flask consisting of a force-increasing electric mixer, a 2000 mL Four-necked flask, temperature-regulated heating jacket, water separator, condenser and other components of the esterification water splitting device for esterification reaction, the crude ester, and then the crude ester were used with a 5% aqueous solution of soda ash, respectively. 5% aqueous soda ash solution, water for neutralization and washing, after removing cyclohexane and water to get 2-phenoxyethyl acrylate.

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