Basic information Reactions Safety Supplier Related

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

Basic information Reactions Safety Supplier Related

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Basic information

Product Name:
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
Synonyms:
  • Bis-(1,1-dimethylethyl)-(1-methyl-2,2-diphenylcyclopropyl)-phosphine
  • Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine
  • Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
  • ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane
  • Mo-Phos
  • cBRIDP(regR)
  • Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine
  • cBRIDP®
CAS:
742103-27-1
MF:
C24H33P
MW:
352.49
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • organophosphine ligand
Mol File:
742103-27-1.mol
More
Less

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Chemical Properties

Melting point:
87-91°C
Boiling point:
427.3±45.0 °C(Predicted)
form 
solid
color 
white to pale yellow
Sensitive 
air sensitive, store cold
CAS DataBase Reference
742103-27-1
More
Less

Safety Information

WGK Germany 
3
HS Code 
2931499090
More
Less

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Usage And Synthesis

Reactions

  1. Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
  2. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
  3. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. 

Uses

Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.

General Description

This product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDPSupplier

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Email
jkinfo@jkchemical.com
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Email
Sales-CN@TCIchemicals.com
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Email
sales.bj@hwrkchemical.com
TCI AMERICA
Tel
800-4238616
Email
sales@tciamerica.com
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Email
product02@bidepharm.com