Basic information Safety Supplier Related

L-ABRINE

Basic information Safety Supplier Related

L-ABRINE Basic information

Product Name:
L-ABRINE
Synonyms:
  • H-METRP-OH
  • L-ABRINE
  • ABRINE
  • ABRINE, L-
  • N-METHYLTRYPTOPHAN
  • N-ME-TRP-OH
  • N-ME-TRP-OH HCL
  • N-ME-TRYPTOPHAN
CAS:
526-31-8
MF:
C12H14N2O2
MW:
218.25
EINECS:
208-388-5
Product Categories:
  • Indoles
  • Tryptophans
  • Amino Acid Derivatives
  • Peptide Synthesis
  • Tryptophan
Mol File:
526-31-8.mol
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L-ABRINE Chemical Properties

Melting point:
>300 °C (dec.)(lit.)
alpha 
D21 +44° (0.28 g in 10 ml 0.5N HCl)
Boiling point:
358.94°C (rough estimate)
Density 
1.272±0.06 g/cm3 (20 ºC 760 Torr)
refractive index 
65 ° (C=1, 0.5mol/L NaOH)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
H2O : 2 mg/mL (9.16 mM; ultrasonic and adjust pH to 10 with NaOH)
form 
Cryst.
pka
2.32±0.10(Predicted)
color 
Off-white to light yellow
optical activity
[α]20/D +65°, c = 1 in 0.5 M NaOH
Merck 
14,10
BRN 
86638
CAS DataBase Reference
526-31-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36
WGK Germany 
3
HS Code 
29339900

MSDS

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L-ABRINE Usage And Synthesis

Chemical Properties

white to light grey crystalline powder or crystals

Uses

L-Abrine is an indoleamino acid that displays radical scavenging and antioxidant properties.

Definition

ChEBI: A N-methyl-L-alpha-amino acid that is the Nalpha-methyl derivative of L-tryptophan.

Biochem/physiol Actions

An indoleamino acid that shows radical scavenging and antioxidant properties in vitro.

Purification Methods

Crystallise L-abrine from H2O or EtOH/H2O mixture and dry it for 2days at 60o in high vacuum; it has m 275-290o(dec with browning at 230o) and [] D +47.2o (c 2, 0.5N HCl) [Peter et al. Helv Chim Acta 46 577 1963]. [Gregory & Morley J Chem Soc 913 1968, Beilstein 22/14 V 40.]

L-ABRINESupplier

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