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Fenpropidin

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Fenpropidin Basic information

Product Name:
Fenpropidin
Synonyms:
  • TERN
  • SPONSOR
  • 1-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)-piperidin
  • 1-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)piperidine
  • 1-(3-(4-tert-butylphenyl)-2-methylpropyl)piperidine
  • cga114900
  • fenpropidine
  • patrol
CAS:
67306-00-7
MF:
C19H31N
MW:
273.46
Product Categories:
  • Alpha sort
  • E-GAlphabetic
  • F
  • FA - FLPesticides
  • Fungicides
  • Others
  • Pesticides&Metabolites
Mol File:
67306-00-7.mol
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Fenpropidin Chemical Properties

Melting point:
25°C
Boiling point:
bp0.2 117°; bp0.045 125°; bp0.032 104°
Density 
0.9112 (rough estimate)
vapor pressure 
1.7 x 10-2 Pa (25 °C)
refractive index 
1.4900 (estimate)
storage temp. 
Refrigerator
solubility 
Chloroform, Ethyl Acetate (Slightly)
pka
10.1
Water Solubility 
530 mg l-1 (pH 7 at 25 °C)
color 
Clear Colourless
Merck 
13,4020
BRN 
5336091
CAS DataBase Reference
67306-00-7
NIST Chemistry Reference
Fenpropidin(67306-00-7)
EPA Substance Registry System
Piperidine, 1-[3-[4-(1,1-dimethylethyl)phenyl]-2-methylpropyl]- (67306-00-7)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
21/22-36
Safety Statements 
26-36/37
RIDADR 
2902
WGK Germany 
3
RTECS 
TM7292000
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29333990
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Fenpropidin Usage And Synthesis

Description

fenpropidine, a piperidine derivative, and spiroxamine, a dioxolanemethyleneamine derivative introduced in 1996 , belong to the same group of fungicides.

Uses

Fenpropidin is a fungicide.

Uses

Agricultural fungicide.

Uses

Fenpropidin is both a contact and a systemic fungicide which provides effective eradicant control of powdery mildew, rusts and leaf blotch in cereal.

Definition

ChEBI: A member of the class of piperidines that is N-isobutylpiperidine in which a hydrogen of one of the methyl groups is replaced by a p-tert-butylphenyl group.

Hazard

Moderately toxic by ingestion, inhalation, and skin contact.

Metabolic pathway

Limited data are available in the open literature. Information presented in this summary is abstracted from the data evaluation published by the Pesticide Safety Directorate (PSD, 1993). Fenpropidin is stable to aqueous hydrolysis and photodegradation. Hydroxylation of the piperidine ring is the primary metabolic pathway in soil and wheat plants. Hydroxylation and oxidation of one of the methyl groups of the tert-butyl moiety are the major reactions in rats and lactating goats. The primary metabolic pathways of fenpropidin are presented in Scheme 1.

Degradation

Fenpropidin (1)i s stable to hydrolytic degradation (50 °C)in the pH range of 3-9 and when exposed to UV light in pH 5 buffer solution.

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