5-ETHYLIDENE-2-NORBORNENE
5-ETHYLIDENE-2-NORBORNENE Basic information
- Product Name:
- 5-ETHYLIDENE-2-NORBORNENE
- Synonyms:
-
- ETHYLIDENE NORBORNENE
- ETHYLIDENE-2-NORBORNENE
- (5E)-5-Ethylidenebicyclo[2.2.1]hept-2-ene
- 2-Norbornene, 5-ethylidene-
- 2-norbornene,5-ethylidene-
- 5-Ethylidene bicyclo[2,2,1]heptene
- 5-ethylidene-2-norbornen
- bicyclo[2.2.1]hept-2-ene,5-ethylidene-
- CAS:
- 16219-75-3
- MF:
- C9H12
- MW:
- 120.19
- EINECS:
- 240-347-7
- Product Categories:
-
- Acyclic
- Alkenes
- Organic Building Blocks
- Mol File:
- 16219-75-3.mol
5-ETHYLIDENE-2-NORBORNENE Chemical Properties
- Melting point:
- -80.15°C
- Boiling point:
- 146 °C(lit.)
- Density
- 0.893 g/mL at 25 °C(lit.)
- vapor density
- 4.1 (vs air)
- vapor pressure
- 4.6 mm Hg ( 20 °C)
- refractive index
- n20/D 1.49(lit.)
- Flash point:
- 101 °F
- storage temp.
- Flammables area
- solubility
- Chloroform (Slightly), Hexanes (Slightly)
- form
- Liquid
- color
- Colorless to Almost colorless
- explosive limit
- ~6.4%
- Water Solubility
- Soluble in water (0.01% at 20C).
- Exposure limits
- ACGIH: TWA 2 ppm; STEL 4 ppm
NIOSH: Ceiling 5 ppm(25 mg/m3) - Stability:
- Volatile
- LogP
- 3.82 at 20℃
- CAS DataBase Reference
- 16219-75-3(CAS DataBase Reference)
- EPA Substance Registry System
- 5-Ethylidene-2-norbornene (16219-75-3)
Safety Information
- Hazard Codes
- Xn,N
- Risk Statements
- 10-22-36/37/38-65-51/53-48/20-43-38-20
- Safety Statements
- 16-26-36/37/39-62-61
- OEL
- Ceiling: 5 ppm (25 mg/m3)
- RIDADR
- UN 2929 6.1/PG 2
- WGK Germany
- 2
- RTECS
- RB9450000
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29021990
- Hazardous Substances Data
- 16219-75-3(Hazardous Substances Data)
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
5-ETHYLIDENE-2-NORBORNENE Usage And Synthesis
Chemical Properties
clear colorless to yellow liquid
Chemical Properties
5-Ethylidene- 2-norbornene is a colorless liquid with a turpentine-like odor. The Odor Threshold is 0.007 ppm.
Uses
Ethylidene norbornene is the third monomer in EPDM (ethylene–propylene diene monomer) elastomers.
Uses
As third monomer in EPDM (ethylene- propylene diene monomer)
Uses
5-Ethylidene-2-norbornene is used as a self healing agent for polymeric composites. It is also used to reinforce multiwalled carbon nanotubes.
Definition
A diene used as the third monomer in EPDM elastomers.
General Description
Colorless liquid with an odor of turpentine. Flash point 101°F. Floats on water.
Air & Water Reactions
Flammable. Insoluble in water.
Reactivity Profile
5-ETHYLIDENE-2-NORBORNENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.
Hazard
Toxic.
Health Hazard
Inhalation of vapors causes headache, confusion, and respiratory distress. Ingestion causes irritation of entire digestive system. Aspiration causes severe pneumonia. Contact with liquid causes irritation of eyes and skin.
Fire Hazard
5-ETHYLIDENE-2-NORBORNENE is flammable.
Safety Profile
Moderately toxic by ingestion. Mildly toxic by inhalation and sh contact. Human systemic effects by inhalation: conjunctiva, olfactory, and taste changes. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Potential Exposure
5-Ethylidene-2-norbornene is used as the third monomer in terpolymer elastomers. Those engaged in the synthesis of pharmaceuticals; pesticides, or in the preparation of specialty resins.
Shipping
UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.
Incompatibilities
May form explosive mixture with air. Reacts violently with strong oxidants. Violent reaction with oxygen and strong oxidizers. May accumulate static electrical charges, and may cause ignition of its vapors. The substance may polymerize. Inhibit peroxide formation with tert-butyl catechol. ENB should be stored in a nitrogen atmosphere since it reacts with oxygen
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
5-ETHYLIDENE-2-NORBORNENE Preparation Products And Raw materials
Raw materials
5-ETHYLIDENE-2-NORBORNENESupplier
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