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2-Methoxy-5-nitrophenol

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2-Methoxy-5-nitrophenol Basic information

Product Name:
2-Methoxy-5-nitrophenol
Synonyms:
  • 5 nitroguaiacol, 2-methoxy-5-nitrophenol
  • Phenol, 2-methoxy-5-nitro-
  • 2-Methoxy-5-nitrophenol 98%
  • 2-METHOXY-5-NITROPHENOL / 5-NITROGUAIACOL
  • 2-METHOXY-5-NITROANILINE
  • 2-Methoxy-5-nitrophenol ,99%
  • 2-Methoxy-5-nitrophe
  • 2-Hydroxy-1-methoxy-4-nitrobenzene
CAS:
636-93-1
MF:
C7H7NO4
MW:
169.13
EINECS:
211-269-0
Product Categories:
  • Aromatic Phenols
  • Phenoles and thiophenoles
  • Building Blocks
  • C6 to C8
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Phenols
Mol File:
636-93-1.mol
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2-Methoxy-5-nitrophenol Chemical Properties

Melting point:
103-107 °C (lit.)
Boiling point:
110-112 °C/1 mmHg (lit.)
Density 
1.3375 (estimate)
refractive index 
1.5830 (rough estimate)
Flash point:
110-112°C/1mm
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
Solid
pka
8.31±0.19(Predicted)
color 
Light Yellow to Light Brown
BRN 
2047074
InChIKey
KXKCTSZYNCDFFG-UHFFFAOYSA-N
CAS DataBase Reference
636-93-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36
RIDADR 
2811
WGK Germany 
3
Hazard Note 
Irritant
PackingGroup 
III
HS Code 
29095090

MSDS

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2-Methoxy-5-nitrophenol Usage And Synthesis

Chemical Properties

Yellow to light brown powder

Uses

2-Methoxy-5-nitrophenol is used in the synthesis of potent VEGF and tyrosine kinase inhibitors. Also used in the synthesis of GABA analogues and phosphodiesterase inhibitors such as rolipram.

Definition

ChEBI: 2-Methoxy-5-nitrophenol is a member of 3-nitrophenols.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 28, p. 1287, 1980 DOI: 10.1248/cpb.28.1287

General Description

2-Methoxy-5-nitrophenol is the substitution photoproduct formed on irradiation of 2-chloro-4-nitroanisole at 25°C in aqueous NaOH.

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