BIS(4-NITROPHENYL) CARBONATE Chemical Properties

Melting point:

136-139 °C(lit.)

Boiling point:

475.9±30.0 °C(Predicted)

Density 

1.501±0.06 g/cm3(Predicted)

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Soluble in chloroform and tetrahydrofuran.

form 

Liquid

color 

Clear slightly yellow or greenish to brown

Sensitive 

Moisture Sensitive

BRN 

1892897

InChIKey

ACBQROXDOHKANW-UHFFFAOYSA-N

CAS DataBase Reference

5070-13-3(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/38

Safety Statements 

26-36

WGK Germany 

3

F 

10-21

HS Code 

29209090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

BIS(4-NITROPHENYL) CARBONATE Usage And Synthesis

Chemical Properties

white to pale yellow or beige powder

Uses

Bis(4-nitrophenyl) carbonate is used as a reagent for preparation of symmetrical and unsymmetrical urea and 4-nitrophenyl esters of N-protected amino acids. It acts as a peptide coupling reagent. It finds application as a reagent for the preparation of carbamate linked cytosines.

Purification Methods

Dissolve the carbonate in CHCl3, wash it with 2N NaOH (3 x) and once with conc HCl, dry (Na2SO4), evaporate and crystallise the residue from toluene (authors say prisms from 15 volumes of *benzene). [Glatthard & Matter Helv Chim Acta 46 795 1963, Beilstein 6 III 820.]

BIS(4-NITROPHENYL) CARBONATE(5070-13-3)Related Product Information

• Methyl pentafluoropropionate
• 4-Nitrosophenol
• 1-(METHOXYMETHOXY)BENZENE
• 4-Nitroanisole
• AMMONIUM CARBONATE
• BIS(2,4-DINITROPHENYL) CARBONATE
• Diphenyl carbonate
• METHYL PHENYL CARBONATE
• BIS(4-NITROPHENYL) CARBONATE
• 4-NITROSOANISOLE
• 4-Nitrophenyl formate
• Ammonium carbonate
• Dimethyl carbonate
• DIPHENOXYMETHANE