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Di(ethylene glycol) vinyl ether

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Di(ethylene glycol) vinyl ether Basic information

Product Name:
Di(ethylene glycol) vinyl ether
Synonyms:
  • Vinyl Carbitol 2-(2-Vinyloxyethoxy)ethanol
  • Diethylene Glycol Monovinyl Ether 
  • Ethanol,2-[2-(ethenyloxy)ethoxy]-
  • Degmve
  • VINYL CARBITOL
  • 2-(2-(ethenyloxy)ethoxy)-ethano
  • 2-(2-(ethenyloxy)ethoxy)ethanol
  • 2-(2-(vinyloxy)ethoxy)-ethano
CAS:
929-37-3
MF:
C6H12O3
MW:
132.16
EINECS:
618-888-9
Product Categories:
  • Ethylene Glycols & Monofunctional Ethylene Glycols
  • Monofunctional Ethylene Glycols
  • Monomers
  • Polymer Science
  • Vinyl Ethers
  • Alcohols and Derivatives
Mol File:
929-37-3.mol
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Di(ethylene glycol) vinyl ether Chemical Properties

Melting point:
-50.3°C
Boiling point:
196 °C(lit.)
Density 
0.968 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.448(lit.)
Flash point:
181 °F
storage temp. 
2-8°C, stored under nitrogen
Water Solubility 
Soluble in water
form 
clear liquid
pka
14.35±0.10(Predicted)
color 
Colorless to Almost colorless
Specific Gravity
1.45
InChI
InChI=1S/C6H12O3/c1-2-8-5-6-9-4-3-7/h2,7H,1,3-6H2
InChIKey
WULAHPYSGCVQHM-UHFFFAOYSA-N
SMILES
C(O)COCCOC=C
CAS DataBase Reference
929-37-3(CAS DataBase Reference)
NIST Chemistry Reference
Ethanol, 2-[2-(ethenyloxy)ethoxy]-(929-37-3)
EPA Substance Registry System
Diethylene glycol monovinyl ether (929-37-3)
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Safety Information

Safety Statements 
23-24/25
RIDADR 
NA 1993 / PGIII
WGK Germany 
2
RTECS 
KM5495500
HazardClass 
CBL
HS Code 
29094400

MSDS

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Di(ethylene glycol) vinyl ether Usage And Synthesis

Chemical Properties

Di(ethylene glycol) vinyl ether (DEGMVE) is a colorless and transparent liquid with a slight odor similar to diethyl ether. It is soluble in water and some organic solvents such as alcohol and ether. Both DEGMVE and DEGDVE are chemical active and easy to be polymerized, and a small amount of NaOH is often added as a polymerization inhibitor.

Synthesis

Acetylene reacts with diethylene glycol in the presence of a catalyst such as potassium hydroxide or potassium diethylene glycol to yield Di(ethylene glycol) vinyl ether (DEGMVE) and Diethylene glycol divinyl ether (DEGDVE):

Uses

Di(ethylene glycol) vinyl ether is an important chemical intermediate compound for the synthesis of other organic materials. In addition, it is an efficient deactivation reagent for olefin complexation catalysts.

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