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1,3:4,6-DI-O-BENZYLIDENE-D-MANNITOL

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1,3:4,6-DI-O-BENZYLIDENE-D-MANNITOL Basic information

Product Name:
1,3:4,6-DI-O-BENZYLIDENE-D-MANNITOL
Synonyms:
  • 1,3,4,6-DI-O-BENZYLIDENE-D-MANNITOL
  • 1,3:4,6-DI-O-BENZYLIDENE-D-MANNITOL
  • 1,3:4,6-bis-O-(phenylMethylene)-D-Mannitol
  • (4R,4'R,5R,5'R)-2,2'-Diphenyl-[4,4'-bi(1,3-dioxane)]-5,5'-diol
  • D-Mannitol, 1,3:4,6-bis-O-(phenylmethylene)-
CAS:
28224-73-9
MF:
C20H22O6
MW:
358.39
Product Categories:
  • 13C & 2H Sugars
  • Carbohydrates & Derivatives
  • Carbohydrate Synthesis
  • Monosaccharides
  • Specialty Synthesis
  • Aromatics
  • Heterocycles
Mol File:
28224-73-9.mol
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1,3:4,6-DI-O-BENZYLIDENE-D-MANNITOL Chemical Properties

Melting point:
192-195 °C
Boiling point:
595.4±50.0 °C(Predicted)
Density 
1.312±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
Acetone (Slightly), Methanol ()Slightly
form 
Solid
pka
12.96±0.60(Predicted)
color 
White
optical activity
[α]20/D 8.4±0.3°, c = 1% in acetone
BRN 
1627753
CAS DataBase Reference
28224-73-9(CAS DataBase Reference)
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Safety Information

WGK Germany 
3
21
HS Code 
29329990

MSDS

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1,3:4,6-DI-O-BENZYLIDENE-D-MANNITOL Usage And Synthesis

Chemical Properties

White Crystalline Solid

Uses

1,3:4,6-Di-O-benzylidene-D-mannitol (cas# 28224-73-9) is a compound useful in organic synthesis.

Purification Methods

1,3,4,6-Di-O-benzylidene-D-mannitol recrystallises from Et2O in long fine needles with at 256nm ( 435) in 95% EtOH, RF 0.21 (1:1 CCl4/EtOAc) on TLC Silica Gel G. [Sinclair Carbohydr Res 12 150 1970, ORD, CD, NMR, IR, MS: Brecknell et al. Aust J Chem 29 1749 1976, Beilstein 19/11 V 640.]

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