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SODIUM DIHYDROGEN CITRATE

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SODIUM DIHYDROGEN CITRATE Basic information

Product Name:
SODIUM DIHYDROGEN CITRATE
Synonyms:
  • 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, sodium salt (1:1)
  • Sodium dihydrogen citrate Anhydrous
  • CITRICACID,MONOSODIUMSALT(ANHYDROUS)
  • Natriumdihydrogencitrat
  • Sodium citrate: (Monosodium citrate)
  • Citric acid monosodium salt, Sodium citrate monobasic
  • Citric acid monosodium salt, Sodium dihydrogen citrate
  • Sodium citrate monobasic anhydrous
CAS:
18996-35-5
MF:
C6H9NaO7
MW:
216.12
EINECS:
242-734-6
Mol File:
18996-35-5.mol
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SODIUM DIHYDROGEN CITRATE Chemical Properties

Melting point:
212 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
H2O: 0.25 M at 20 °C, clear, colorless
form 
Crystalline Powder
color 
White
Odor
Odorless
PH
4.07(1 mM solution);3.87(10 mM solution);3.71(100 mM solution);3.48(1000 mM solution)
Water Solubility 
Soluble in water. Insoluble in ethanol.
λmax
λ: 260 nm Amax: 0.15
λ: 280 nm Amax: 0.05
BRN 
3920246
InChI
InChI=1S/C6H8O7.Na.H/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;
InChIKey
JKYDHHIKDADVTE-UHFFFAOYSA-N
SMILES
C(O)(C(=O)O)(CC(=O)O)CC(=O)O.[NaH]
CAS DataBase Reference
18996-35-5(CAS DataBase Reference)
EPA Substance Registry System
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, monosodium salt (18996-35-5)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36
Safety Statements 
22-24/25
WGK Germany 
1
RTECS 
GE7950000
3
TSCA 
Yes
HS Code 
29181500

MSDS

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SODIUM DIHYDROGEN CITRATE Usage And Synthesis

Description

Mono sodium citrate, or sodium dihydrogen citrate, is an acid salt with the chemical formula NaH2C6H5O7, or C3H4OH(COOH)2COONa. Since it has two remaining open spots on the citrate anion, it is used as a relatively strong sequestrant. It is used to prevent platelet clumping in blood samples. It is one of the 3 citric acid salts.

Chemical Properties

white crystalline powder

Uses

Sodium dihydrogencitrate has been employed:

  • as reductant and stabilizer during the synthesis of Fe3O4 Pt core/shell particles
  • in characterization of carbon-based electrode materials as cathode in half-cell configuration
  • in electrochemical reduction of proton at carbon fiber electrode in the presence and absence of Pt nanoparticles

Uses

Sodium dihydrogen citrate acts as a buffering agent and sequestrant. It is also employed as a reductant and stabilizer in the preparation of b>Fe3O4 platinum core/shell particles. Further, it is used in electrochemical reduction of proton at carbon fiber electrode in the presence and absence of platinum nanoparticles. In addition to this, it plays a useful role in characterization of carbon-based electrode materials as cathode in half-cell configuration.

Preparation

Monosodium citrate can be prepared by the direct reaction of sodium carbonate or bicarbonate with citric acid:
NaHCO3(s) + C6H8O7 (aq) → NaC6H7O7 (aq) + CO2 (g) + H2O (l).

General Description

Sodium citrate is a useful setting retardant for improvement of properties of brushite cement.

Flammability and Explosibility

Non flammable

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