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(+)-DIHYDROCARVONE MIXTURE OF ISOMERS

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(+)-DIHYDROCARVONE MIXTURE OF ISOMERS Basic information

Product Name:
(+)-DIHYDROCARVONE MIXTURE OF ISOMERS
Synonyms:
  • (2S,5R)-2-methyl-5-(1-methylethenyl)-1-cyclohexanone
  • (+)-dihydrocarvone,mixtureofisomers
  • (2theta-trans)-cyclohexanon
  • 2-methyl-5-(1-methylethenyl)-,(2R-trans)-Cyclohexanone
  • Carvone,dihydro-
  • Cyclohexanone,2-methyl-5-(1-methylethenyl)-,(2R,5R)-rel-
  • Cyclohexanone,2-methyl-5-(1-methylethenyl)-,trans-
  • p-Menth-8-en-2-one,trans-
CAS:
5524-05-0
MF:
C10H16O
MW:
152.23
EINECS:
226-872-4
Mol File:
5524-05-0.mol
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(+)-DIHYDROCARVONE MIXTURE OF ISOMERS Chemical Properties

Boiling point:
87-88°C/6mmHg
alpha 
+17°(22℃,neat)
Density 
0.928 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.471
FEMA 
3565 | P-MENTH-8-EN-2-ONE
Flash point:
102 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear
Specific Gravity
0.929
Odor
at 100.00 %. herbal minty mentholic
Odor Type
minty
optical activity
[α]20/D +20±2°, neat
JECFA Number
377
BRN 
2044615
LogP
3.225 (est)
EPA Substance Registry System
Cyclohexanone, 2-methyl-5-(1-methylethenyl)-, (2R,5R)- (5524-05-0)
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Safety Information

Safety Statements 
23-24/25
WGK Germany 
3
HS Code 
29142900
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(+)-DIHYDROCARVONE MIXTURE OF ISOMERS Usage And Synthesis

Chemical Properties

clear liquid

Uses

(+)-Dihydrocarvone may be used in the following processes:

  • Synthesis of dispiro 1,2,4,5-tetraoxanes, which show potent anti-malarial activity.
  • Synthesis of an epoxylactone by oxidation, which can undergo copolymerization with ε-caprolactone to form cross-linked copolymers with shape memory properties.
  • Synthesis of α-Cyperone, a eudesmane type sesquiterpenoid compound with potent insecticidal activity.

Definition

ChEBI: A dihydrocarvone in (R,R) configuration.

General Description

(+)-Dihydrocarvone, a monoterpenoid compound found in caraway oil, is a key building block to synthesize sesquiterpenes. It is generally produced either by the hydrogenation of carvone or oxidation of limonene.

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