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(+)-DIHYDROCARVONE

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(+)-DIHYDROCARVONE Basic information

Product Name:
(+)-DIHYDROCARVONE
Synonyms:
  • P-MENTH-8-EN-2-ONE
  • (Z)-dihydrocarvone
  • 2-methyl-5-(1-methylethenyl)-cyclohexanon
  • 2-Methyl-5-(1-methylethenyl)cyclohexanone
  • 2-methyl-5-(1-methylethenyl)-Cyclohexanone
  • 5-Isopropenyl-2-methylcyclohexanone
  • cis-Dihydrocarvone
  • Cyclohexanone, 2-methyl-5-(1-methylethenyl)-
CAS:
7764-50-3
MF:
C10H16O
MW:
152.23
EINECS:
231-857-0
Product Categories:
  • Chiral Building Blocks
  • Ketones
  • Organic Building Blocks
Mol File:
7764-50-3.mol
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(+)-DIHYDROCARVONE Chemical Properties

Boiling point:
87-88 °C6 mm Hg(lit.)
Density 
0.929 g/mL at 25 °C(lit.)
vapor density 
5.2 (vs air)
vapor pressure 
0.06 mm Hg ( 20 °C)
refractive index 
n20/D 1.472(lit.)
FEMA 
3565 | P-MENTH-8-EN-2-ONE
Flash point:
178 °F
storage temp. 
2-8°C
Odor
at 100.00 %. warm powerful herbal spearmint
Odor Type
minty
optical activity
[α]22/D +17°, neat
JECFA Number
377
Dielectric constant
8.5(19℃)
LogP
2.85
CAS DataBase Reference
7764-50-3
EPA Substance Registry System
Cyclohexanone, 2-methyl-5-(1-methylethenyl)- (7764-50-3)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
RTECS 
OT0305000

MSDS

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(+)-DIHYDROCARVONE Usage And Synthesis

Chemical Properties

p-Menth-8-en-2-one has an herbaceous, spearmint-like odor.

Occurrence

Reported present in oregano oil, celery, spearmint oil, scotch spearmint oil, thymus, dill herb and seed and caraway seed.

Uses

The dual, herbal-minty quality of this compound will add an interesting twist to mint flavors as well as to celery, caraway, dill and herbal flavors, especially intended for cough drops and oral care products. At very low levels, it will add depth to tropical flavors like lychee, guava, passion fruit and rambutan.

Uses

The N-functionalization of dihydrocarvone forms imine derivatives, which are synthons for preparing N-heterocycles.

Definition

ChEBI: A dihydrocarvone resulting from reduction of the endocyclic cyclohexene double bond.

Aroma threshold values

Detection: 820 ppb to 1.06 ppm

Synthesis Reference(s)

Journal of the American Chemical Society, 89, p. 2794, 1967 DOI: 10.1021/ja00987a087
Tetrahedron Letters, 30, p. 6567, 1989 DOI: 10.1016/S0040-4039(01)89023-7

General Description

Natural occurence: Caraway seed, celery seed, dill, patchouli, spearmint, buchu and pepper

Biochem/physiol Actions

Taste at 2-4ppm

Safety Profile

Moderately toxic by subcutaneous route. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

(+)-DIHYDROCARVONE Preparation Products And Raw materials

Raw materials

(+)-DIHYDROCARVONESupplier

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