S-TERT-BUTYL THIOACETATE Chemical Properties

Boiling point:

135-136 °C (lit.)

Density 

0.927 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.453(lit.)

Flash point:

93 °F

BRN 

1740436

LogP

2.133 (est)

Safety Information

Risk Statements 

10

Safety Statements 

23-24/25

RIDADR 

UN 1993 3/PG 3

WGK Germany 

3

F 

9-13

HazardClass 

3.2

PackingGroup 

III

MSDS

• Language:English Provider:SigmaAldrich

S-TERT-BUTYL THIOACETATE Usage And Synthesis

Uses

S-tert-Butyl thioacetate may be used for the preparation of vinyloxyborane derivative.

General Description

S-tert-Butyl thioacetate is a thioester.

Purification Methods

Dissolve it in CHCl3 (EtOH-free), wash with H2O, 10% H2SO4, saturated aqueous NaHCO3 (care CO2 liberated), H2O again, dry over Drierite and anhydrous K2CO3, and fractionate under reduced pressure. [Rylander & Tarbell J Am Chem Soc 72 3021 1950, Beilstein 2 IV 546.]

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