ChemicalBook > Product Catalog > Organic Chemistry > Heterocyclic Compounds > (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Basic information
- Product Name:
- (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- Synonyms:
-
- tricyclohexylphosphinecyclooctadienepyridineiridium PF6
- Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex
- (TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTA- DIENE)(PYRIDINE)IRIDIUM(I) PF6
- (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,99%
- (1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate
- (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I)hexafluorophosphate,99%CRABTREE'SCATALYST
- 1,5-Cyclooctadiene-(pyridyl)-(tricyclohexylphosphine)-iridium hexafluoropho
- (cycloocta-1,5-diene)pyridyl(tricyclohexyl-phosphine)iridium(I)hexafluorophosphate Crabtree's catalyst
- CAS:
- 64536-78-3
- MF:
- C31H47F6IrNP2
- MW:
- 801.88
- Product Categories:
-
- Ir
- Mol File:
- 64536-78-3.mol
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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties
- Melting point:
- 175 °C (dec.)(lit.)
- Density
- 1.67 g/cm3
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Chloroform (Slightly)
- form
- Crystalline Powder
- color
- Orange
- Water Solubility
- Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.
- Sensitive
- Moisture Sensitive
- Merck
- 13,2594
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MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Usage And Synthesis
Reaction
- Iridium catalyst used for the highly enantioselective hydrogenation of α,β-unsaturated esters.
- Iridium catalyst used for the stereoselective catalytic hydrogenation and conjugate reduction of 4methylitaconate derivatives bearing a chiral auxiliary.
- Iridium catalyst used in the synthesis of thiophene-based TAK-779 analogues via C-H arylation.
- Iridium catalyst used in the practical synthetic approach to chiral (α-chloroalkyl)boronic esters via an iridiumcatalyzed, chemoselective hydrogenation of chloro-substituted alkenyl boronates.
- Iridium catalyst used in the regioselective C-H activation and hydrogen-isotope exchange of non-aromatic unsaturated functionality.
Chemical Properties
orange crystals
Uses
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATESupplier
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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE(64536-78-3)Related Product Information
- Ruthenium(III) chloride hydrate
- GRUBBS CATALYST 2ND GENERATION
- (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
- 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
- DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II)
- Dimethyl sulfoxide
- DI-I-PROPYLPHOSPHINE
- Tricyclohexyl phosphine
- TRIHEXYLPHOSPHINE
- TRIISOPROPYLPHOSPHINE
- DICYCLOHEXYLPHOSPHINE
- 1,5-Cyclooctadiene
- CYCLOHEXYLPHOSPHINE
- (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE